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CAS 14099-01-5

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pentacarbonylchlororhenium

Description:
Pentacarbonylchlororhenium is a coordination compound featuring rhenium, a transition metal known for its complex chemistry. This substance is characterized by its coordination of five carbonyl (CO) ligands and one chloride (Cl) ligand to a central rhenium atom. The presence of carbonyl groups imparts significant stability and unique electronic properties, allowing for interesting reactivity patterns. Pentacarbonylchlororhenium typically appears as a solid at room temperature and is sensitive to air and moisture, necessitating careful handling under inert atmospheres. Its molecular structure exhibits a trigonal bipyramidal geometry, which is common for such metal carbonyl complexes. The compound is of interest in various fields, including catalysis and materials science, due to its potential applications in organic synthesis and as a precursor for other rhenium-containing compounds. Additionally, the reactivity of the carbonyl ligands can facilitate further chemical transformations, making pentacarbonylchlororhenium a valuable compound in organometallic chemistry.
Formula:C5ClO5Re
InChI:InChI=1/5CO.ClH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1/r5CO.ClRe/c6*1-2
InChI key:InChIKey=JQUUAHKBIXPQAP-UHFFFAOYSA-M
SMILES:[Re+](C#O)(C#O)(C#O)(C#O)(C#O)[Cl-]
Synonyms:
  • (OC-6-22)-Pentacarbonylchlororhenium
  • Carbon Monooxide - Chlororhenium (5:1)
  • Chloropentacarbonylrhenium
  • Chloropentacarbonylrhenium(I)
  • Chlororhenium pentacarbonyl
  • Pentacarbonylchlororhenium(I)
  • Pentacarbonylrhenium chloride
  • Rhenium carbonyl chloride (Re(CO)<sub>5</sub>Cl)
  • Rhenium pentacarbonyl chloride
  • Rhenium, chloropentacarbonyl-
  • See more synonyms
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