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CAS 14100-30-2

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Pentacarbonylchloromanganese

Description:
Pentacarbonylchloromanganese, with the CAS number 14100-30-2, is a coordination compound featuring manganese in a low oxidation state, typically +1. This compound is characterized by its coordination of five carbonyl (CO) ligands and one chloride (Cl) ligand to the manganese center. The presence of carbonyl ligands imparts significant stability and unique electronic properties to the complex, making it a subject of interest in organometallic chemistry. Pentacarbonylchloromanganese is generally a volatile, air-sensitive substance that requires careful handling under inert atmospheres to prevent degradation. Its reactivity can be attributed to the presence of the manganese center, which can participate in various chemical transformations, including substitution reactions and redox processes. The compound is often utilized in synthetic applications and as a precursor in the preparation of other manganese-containing complexes. Additionally, its study contributes to the understanding of metal-carbonyl interactions and the role of transition metals in catalysis.
Formula:C5ClMnO5
InChI:InChI=1S/5CO.ClH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InChI key:InChIKey=MIPGCUSUYZTDPC-UHFFFAOYSA-M
SMILES:[Mn+](C#O)(C#O)(C#O)(C#O)(C#O)[Cl-]
Synonyms:
  • Manganese, pentacarbonylchloro-, (OC-6-22)-
  • (OC-6-22)-Pentacarbonylchloromanganese
  • Pentacarbonylchloromanganese
  • Manganese, pentacarbonylchloro-
  • Manganese, chloropentacarbonyl-
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