CAS 14220-21-4: Bromopentacarbonylrhenium
Description:Bromopentacarbonylrhenium, with the CAS number 14220-21-4, is a coordination compound of rhenium that features a central rhenium atom surrounded by five carbonyl (CO) ligands and one bromine atom. This compound is characterized by its distinctive coordination geometry, typically exhibiting a trigonal bipyramidal arrangement due to the presence of the five carbonyl groups. The carbonyl ligands contribute to the compound's stability and reactivity, as they can engage in π-backbonding with the rhenium center. Bromopentacarbonylrhenium is often utilized in organometallic chemistry and catalysis, particularly in reactions involving carbonylation processes. Its properties include moderate solubility in organic solvents and sensitivity to moisture, which can lead to hydrolysis. The compound's reactivity can be influenced by the presence of the bromine ligand, which can participate in substitution reactions. Overall, bromopentacarbonylrhenium serves as an important precursor in the synthesis of various rhenium-containing complexes and has applications in materials science and catalysis.
Formula:C5BrO5Re
InChI:InChI=1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InChI key:InChIKey=NWJBOTGGBYFKEJ-UHFFFAOYSA-M
SMILES:O#C[Re+]([Br-])(C#O)(C#O)(C#O)C#O
- Synonyms:
- Bromopentacarbonylrhenium
- Bromopentacarbonylrhenium(I)
- Carbon Monooxide - Bromorhenium (5:1)
- Pentacarbonylbromorhenium
- Pentacarbonylrhenium bromide
- Pentacarbonylrhenium bromide (Re(CO)<sub>5</sub>Br)
- Re(CO)<sub>5</sub>Br
- Rhenium(I) pentacarbonyl bromide
- Rhenium, bromopentacarbonyl-
- Rhenium, bromopentacarbonyl-, (OC-6-22)-
- See more synonyms
- Pentacarbonylrhenium bromide (Re(CO)5Br)
- Rhenium pentacarbonyl bromide

Bromopentacarbonylrhenium(I), 98%
Ref: 02-042097
1g | 305.00 € |

Rhenium pentacarbonyl bromide, 98%
Ref: 08-75-0150
1g | 202.00 € | ||
5g | 764.00 € | ||
250mg | 121.00 € |

Rhenium, bromopentacarbonyl-, (OC-6-22)- (9CI)
Ref: IN-DA001HY9
1g | 664.00 € | ||
100mg | 148.00 € | ||
250mg | 202.00 € |

Bromopentacarbonylrhenium(I)
Controlled ProductRef: TR-B740015
1g | 846.00 € | ||
250mg | 348.00 € | ||
500mg | 534.00 € |

Bromopentacarbonylrhenium(I)
Controlled ProductRef: 3D-PAA22021
1g | Discontinued | Request information | |
50mg | Discontinued | Request information | |
100mg | Discontinued | Request information | |
250mg | Discontinued | Request information | |
500mg | Discontinued | Request information |