CAS 14220-64-5

Bis(benzonitrile)dichloropalladium

Description:

Bis(benzonitrile)dichloropalladium, with the CAS number 14220-64-5, is a coordination compound of palladium characterized by its two benzonitrile ligands and two chloride ions. This compound typically appears as a solid and is known for its role as a catalyst in various organic reactions, particularly in cross-coupling reactions such as the Suzuki and Heck reactions. The palladium center in this compound exhibits a square planar geometry, which is common for palladium(II) complexes. The presence of benzonitrile ligands, which are aromatic nitriles, contributes to the stability and reactivity of the complex. Additionally, the compound is sensitive to air and moisture, necessitating careful handling and storage under inert conditions. Its applications in synthetic organic chemistry make it valuable for the formation of carbon-carbon bonds, facilitating the development of complex organic molecules. Overall, bis(benzonitrile)dichloropalladium is an important reagent in modern chemical synthesis, particularly in the field of pharmaceuticals and materials science.

Formula: C₁₄H₁₀Cl₂N₂Pd

InChI: InChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key: InChIKey=WXNOJTUTEXAZLD-UHFFFAOYSA-L

SMILES: C(#[N][Pd+2]([N]#CC1=CC=CC=C1)([Cl-])[Cl-])C2=CC=CC=C2

Synonyms:

• Benzonitrile, palladium complex
• Benzonitrile-Dichloropalladium (2:1)
• Bis(benzonitril)palladiumchlorid
• Bis(benzonitrile)dichloropalladium
• Bis(benzonitrile)dichloropalladium ii
• Bis(benzonitrile)palladium chloride
• Bis(benzonitrile)palladium dichloride
• Bis(benzonitrile)palladium(2+) chloride
• Bis(phenylnitrile)dichloropalladium
• Chlorure De Bis(Benzonitrile)Palladium
• Cloruro De Bis(Benzonitrilo)Paladio
• Dibenzonitrilepalladium dichloride
• Dichlorobis(benzonitrile)palladium
• Dichlorobis(benzonitrile)palladium(II)
• Dichlorobis(phenyl cyanide)palladium
• Nsc 169967
• Palladium chloride bisbenzonitrile complex
• Palladium dichloride bis(benzonitrile)
• Palladium, bis(benzonitrile)dichloro-
• Palladium, dichlorobis(benzonitrile)-
• trans-Bis(benzonitrile)dichloropalladium(II)

Bis(benzonitrile)palladium(II) Dichloride

CAS: 14220-64-5

Formula: C₁₄H₁₀Cl₂N₂Pd

Purity: >98.0%(T)

Color and Shape: Light yellow to Brown powder to crystal

Molecular weight: 383.57

Ref: 3B-B1668

Bis(Benzonitrile)palladium (II) chloride

CAS: 14220-64-5

Purity: 98%

Molecular weight: 381.93

Ref: 10-F035786

trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.1%

CAS: 14220-64-5

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Sci

Formula: C₁₄H₁₀Cl₂N₂Pd

Molecular weight: 383.57

Ref: 02-010006

Dichlorobis(benzonitrile)palladium(II), 99%

CAS: 14220-64-5

Dichlorobis(benzonitrile)palladium(II), 99%

Formula: PdCl₂(C₆H₅CN)₂

Purity: 99%

Color and Shape: yellow to orange pwdr.

Molecular weight: 383.55

Ref: 08-46-0400

Bis(benzonitrile)palladium chloride

CAS: 14220-64-5

Formula: C₁₄H₁₀Cl₂N₂Pd

Purity: 98%

Color and Shape: Solid

Molecular weight: 383.5686

Ref: IN-DA003OA4

Bis(benzonitrile)palladium(II) chloride

CAS: 14220-64-5

Bis(benzonitrile)palladium(II) chloride

Formula: ·Cl₂Pd·2C₆H₅CN

Purity: 99%

Color and Shape: yellow solid

Molecular weight: 383.57g/mol

Ref: 54-OR46569

Dichlorobis(benzonitrile) palladium(II)

CAS: 14220-64-5

Formula: (C₆H₅CN)₂PdCl₂

Molecular weight: 383.55

Ref: 7W-GX4755

Bis(benzonitrile)palladium(II) Dichloride extrapure, 27.4% Pd

CAS: 14220-64-5

Formula: (C₆H₅CN)₂PdCl₂

Color and Shape: Yellow to Orange, Powder

Molecular weight: 383.57

Ref: SR-11866

Bis(benzonitrile)palladium(II) Chloride

Controlled Product

CAS: 14220-64-5

Formula: C₁₄H₁₀Cl₂N₂Pd

Color and Shape: Neat

Molecular weight: 383.57

Ref: TR-B204608

Bis(Benzonitrile)palladium(II) chloride

Controlled Product

CAS: 14220-64-5

Bis(benzonitrile)palladium(II) chloride is a palladium complex with the coordination geometry of square-planar. It has been shown to undergo a suzuki coupling reaction when reacted with an aromatic hydrocarbon, such as benzene or toluene, in the presence of sodium carbonate and nitrogen gas. This reaction produces an intramolecular hydrogen bond between the oxygen atom of the hydroxyl group and the nitrogen atom on the chelate ligand. Bis(benzonitrile)palladium(II) chloride has also been shown to be useful for generating x-ray crystal structures of metal complexes by using ft-ir spectroscopy. The chlorine atom from bis(benzonitrile)palladium(II) chloride may react with hydrochloric acid to produce a soluble complex that can be isolated by crystallography.

Formula: C₁₄H₁₀Cl₂N₂Pd

Purity: Min. 95%

Molecular weight: 383.57 g/mol

Ref: 3D-FB54980