CAS 14264-16-5

Bis(triphenylphosphine)nickel dichloride

Description:

Bis(triphenylphosphine)nickel dichloride, with the CAS number 14264-16-5, is a coordination compound featuring a nickel center coordinated by two triphenylphosphine ligands and two chloride ions. This compound typically exhibits a square planar geometry, which is characteristic of nickel(II) complexes. The presence of the bulky triphenylphosphine ligands contributes to its stability and solubility in organic solvents. It is often used in organic synthesis and catalysis, particularly in reactions involving cross-coupling and other transition metal-catalyzed processes. The compound is generally air-stable but should be handled with care due to its potential toxicity and the presence of nickel, which can pose health risks. Its reactivity can be influenced by the nature of the ligands and the reaction conditions, making it a valuable tool in synthetic chemistry. Additionally, it can serve as a precursor for other nickel complexes and is studied for its electronic properties and potential applications in materials science.

Formula: C₃₆H₃₀Cl₂NiP₂

InChI: InChI=1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChI key: InChIKey=ZBRJXVVKPBZPAN-UHFFFAOYSA-L

SMILES: [P]([Ni+2]([P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)([Cl-])[Cl-])(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6

Synonyms:

• Dichlorobis(triphenylphosphine)nickel(II)
• [Bis(triphenylphosphine)]dichloroNickel(II)
• Nickel(2+) Chloride-Triphenylphosphane (1:2:2)
• Dichloronickel
• Triphenylphosphonium
• Bis(tri-N-butylphosphine)dichloronickel
• Bis(triphenylphosphine)nickel(II)dichloride
• Bis(Triphenyl Phosphine)Nickel(Ii) Chloride
• Bis(triphenylphosphin)nickel(II)chlorid
• Bis(triphenylphosphine)dichloronickel
• Bis(triphenylphosphine)nickel dichloride
• Chlorure de bis(triphenylphosphine)nickel(II)
• cloruro de bis(trifenilfosfina)niquel(II)
• Dichlorobis(triphenylphosphine)nickel
• Nickel, dichlorobis(triphenylphosphine)-

Bis(triphenylphosphine)nickel(II) Dichloride

CAS: 14264-16-5

Formula: C₃₆H₃₀Cl₂NiP₂

Purity: >96.0%(T)

Color and Shape: Dark green to Dark blue to Black powder to crystal

Molecular weight: 654.18

Ref: 3B-B1571

Bis(triphenylphosphine)dichloronickel

CAS: 14264-16-5

Purity: 98%

Color and Shape: Solid

Molecular weight: 656.1900024414062

Ref: 10-F788438

Bis(triphenylphosphine)nickel(II) chloride, 99%

CAS: 14264-16-5

Bis(triphenylphosphine)nickel(II) chloride, 99%

Formula: (C₆H₅)₃PNiCl₂

Purity: 99%

Color and Shape: green xtl.

Molecular weight: 654.20

Ref: 08-28-0095

Bis(triphenylphosphine)nickel(II)chloride

CAS: 14264-16-5

Formula: C₃₆H₃₀Cl₂NiP₂

Purity: 98%

Color and Shape: Solid

Molecular weight: 654.1703

Ref: IN-DA0034J8

Bis(triphenylphosphine)dichloronickel

CAS: 14264-16-5

Bis(triphenylphosphine)dichloronickel

Purity: 98%

Molecular weight: 654.17g/mol

Ref: 54-OR75540

Bis(triphenylphosphine)nickel (II) chloride

CAS: 14264-16-5

Formula: (C₆H₅)₃PNiCI₂

Color and Shape: Green to dark-grey crystalline powder

Molecular weight: 654.17

Ref: 7W-GX9818

Bis(triphenylphosphine)nickel(II) dichloride

CAS: 14264-16-5

Bis(triphenylphosphine)nickel(II) dichloride is a coordination compound that belongs to the group P2. It has an octahedral geometry with two adjacent nickel atoms and two chloride ligands. The metal-metal bond length is 2.14 Å, which is shorter than the average bond length of 2.54 Å for octahedral complexes. Bis(triphenylphosphine)nickel(II) dichloride reacts with quinoline derivatives to form amines and undergoes transfer reactions with amines, chlorides, and olefins. It also undergoes irreversible oxidation when in contact with water. The compound is stereoselective for substitution by halides at the para position on the phenyl ring.

Formula: C₃₆H₃₀Cl₂NiP₂

Purity: Min. 95%

Color and Shape: Powder

Molecular weight: 654.17 g/mol

Ref: 3D-FB18764

Bis(triphenylphosphine)nickel(II) chloride

CAS: 14264-16-5

Formula: C₃₆H₃₀Cl₂NiP₂

Purity: 96%

Color and Shape: Solid, Crystalline Powder or Lumps or Powder

Molecular weight: 652.055

Ref: 10-F049727

Bis(triphenylphosphine)nickel(II) Dichloride

Controlled Product

CAS: 14264-16-5

Formula: C₁₈H₁₅P·Cl₂Ni

Color and Shape: Neat

Molecular weight: 654.17

Ref: TR-B588700