CAS 142962-95-6

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)

Description:

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II), commonly referred to as Ru(bisphosphine), is a coordination complex of ruthenium featuring a chiral bisphosphine ligand. This compound is characterized by its octahedral geometry, where the ruthenium center is coordinated to two acetate groups and a bidentate phosphine ligand. The presence of the chiral bisphosphine ligand imparts stereochemical properties, making it useful in asymmetric catalysis. The compound is typically soluble in organic solvents, which enhances its applicability in various chemical reactions. Its reactivity is influenced by the electronic properties of the phosphine ligands and the acetate groups, allowing it to participate in catalytic cycles, particularly in hydrogenation and cross-coupling reactions. Additionally, the compound's stability and selectivity in catalysis are notable, making it a valuable reagent in synthetic organic chemistry. Safety data should be consulted, as with all metal complexes, due to potential toxicity associated with ruthenium compounds.

Formula: C₄₈H₄₆O₄P₂Ru

Synonyms:

• (S)-Ru(OAc)2(H8-BINAP)
• Diacetato[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]ruthenium(II)

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)₂[(S)-H₈-binap]

CAS: 142962-95-6

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap]

Formula: C₄₈H₄₆O₄P₂Ru

Color and Shape: yellow to dark brown solid

Molecular weight: 849.89

Ref: 08-44-0167

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II)

CAS: 142962-95-6

Formula: C₉₂H₈₆O₄P₄Ru₂

Color and Shape: Solid

Molecular weight: 1581.6999

Ref: IN-DA003COC

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II)

CAS: 142962-95-6

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II)

Purity: 98%

Molecular weight: 1581.73g/mol

Ref: 54-IN12941