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CAS 14323-06-9

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Tris(2,2′-bipyridyl)ruthenium(II) chloride

Description:
Tris(2,2′-bipyridyl)ruthenium(II) chloride, commonly referred to as Ru(bpy)₃Cl₂, is a coordination complex of ruthenium with notable photophysical properties. It features a central ruthenium ion coordinated to three 2,2′-bipyridine ligands and two chloride ions. This compound is characterized by its vibrant red color and strong luminescence, making it a popular choice in photochemistry and electrochemistry studies. Ru(bpy)₃Cl₂ exhibits a stable oxidation state of +2 and can undergo oxidation to form a Ru(bpy)₃³⁺ species, which is crucial for various applications, including light-harvesting systems and as a photosensitizer in photodynamic therapy. The complex is soluble in polar solvents, such as water and methanol, and its stability and reactivity can be influenced by the pH of the solution. Additionally, it has been extensively studied for its role in catalysis and as a probe in biological systems due to its ability to interact with biomolecules. Overall, Ru(bpy)₃Cl₂ is a versatile compound with significant implications in both fundamental research and practical applications.
Formula:C30H24N6Ru·2Cl
InChI:InChI=1S/3C10H8N2.2ClH.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2
InChI key:InChIKey=SJFYGUKHUNLZTK-UHFFFAOYSA-L
SMILES:[Ru+2]123([N]=4C(C=5[N]1=CC=CC5)=CC=CC4)([N]=6C(C=7[N]2=CC=CC7)=CC=CC6)[N]=8C(C=9[N]3=CC=CC9)=CC=CC8.[Cl-]
Synonyms:
  • 2,2'-Bipyridine, Ruthenium(2+) Salt (3:1)
  • Dichlorotris(2,2′-bipyridyl)ruthenium(II)
  • Nsc 71326
  • Ruthenium tris(2,2'-bipyridine)-, dichloride
  • Ruthenium tris(2,2′-bipyridyl) dichloride
  • Ruthenium(2+) Chloride-2,2'-Bipyridine (1:2:3)
  • Ruthenium(2+), tris(2,2'-bipyridine)-, dichloride
  • Ruthenium(2+), tris(2,2'-bipyridine-N,N')-, dichloride, (OC-6-11)-
  • Ruthenium(2+), tris(2,2'-bipyridine-kappaN1,kappaN1')-, chloride (1:2), (OC-6-11)-
  • Ruthenium(2+), tris(2,2'-bipyridine-kappaN1,kappaN1')-, dichloride, (OC-6-11)-
  • See more synonyms
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