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CAS 14434-47-0

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(OC-6-11)-Tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)chromium

Description:
(OC-6-11)-Tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)chromium, commonly referred to as chromium(III) tris(2,2,6,6-tetramethyl-3,5-heptanedionate), is a coordination compound characterized by its complex structure involving a chromium ion coordinated to three bidentate ligands derived from 2,2,6,6-tetramethyl-3,5-heptanedione. This compound typically exhibits a deep red to purple color, indicative of its chromophoric properties, and is known for its stability and solubility in organic solvents. The presence of bulky tetramethyl groups in the ligands contributes to steric hindrance, which can influence the reactivity and coordination chemistry of the chromium center. It is often used in various applications, including catalysis, materials science, and as a precursor in the synthesis of chromium-containing materials. Additionally, its unique ligand field can lead to interesting electronic and magnetic properties, making it a subject of study in coordination chemistry and materials research. Safety data should be consulted, as chromium compounds can pose health risks depending on their oxidation state and exposure levels.
Formula:C33H57CrO6
InChI:InChI=1S/3C11H19O2.Cr/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7H,1-6H3;/q3*-1;+3
InChI key:InChIKey=JVCUBTDSDFCNLM-UHFFFAOYSA-N
SMILES:C(C)(C)(C)C1=O[Cr+3]23(O=C(C(C)(C)C)[CH-]C(C(C)(C)C)=O2)(O=C(C(C)(C)C)[CH-]C(C(C)(C)C)=O3)O=C(C(C)(C)C)[CH-]1
Synonyms:
  • (OC-6-11)-Tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO<sup>3</sup>,κO<sup>5</sup>)chromium
  • 3,5-Heptanedione, 2,2,6,6-tetramethyl-, chromium complex
  • Chromium iii 2,2,6,6-tetramethylheptanedionate
  • Chromium tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
  • Chromium tris(dipivaloylmethanate)
  • Chromium(III) 2,2,6,6-tetramethyl-3,5-heptanedionate
  • Chromium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato)-
  • Chromium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O′)-, (OC-6-11)-
  • Chromium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO,κO′)-, (OC-6-11)-
  • Chromium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO<sup>3</sup>,κO<sup>5</sup>)-, (OC-6-11)-
  • See more synonyms
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