CAS 14647-23-5

(Bis(diphenylphosphino)ethane)dichloronickel

Description:

(Bis(diphenylphosphino)ethane)dichloronickel, commonly referred to as NiCl2(dppeth), is a coordination compound featuring nickel in a +2 oxidation state coordinated to two diphenylphosphinoethane ligands and two chloride ions. This compound typically exhibits a square planar geometry due to the d8 electron configuration of nickel, which is characteristic of many nickel(II) complexes. The diphenylphosphinoethane ligands contribute to the overall stability and solubility of the complex in organic solvents. NiCl2(dppeth) is often utilized in catalysis, particularly in cross-coupling reactions and other organic transformations, due to its ability to facilitate the transfer of electrons and promote bond formation. The presence of phosphorus donor atoms enhances the reactivity of the nickel center, making it an important compound in organometallic chemistry. Additionally, the compound may exhibit interesting thermal and photochemical properties, which can be relevant in various applications, including materials science and catalysis.

Formula: C₂₆H₂₄Cl₂NiP₂

InChI: InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChI key: InChIKey=XXECWTBMGGXMKP-UHFFFAOYSA-L

SMILES: [Cl-][Ni+2]1([Cl-])[P](CC[P]1(C2=CC=CC=C2)C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5

Synonyms:

• (Bis(diphenylphosphino)ethane)dichloronickel
• 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
• 1,2-Bis(diphenylphosphino)ethanedichloronickel
• 1,2-Bis(diphenylphosphino)ethanenickel dichloride
• 1,2-Ethylenebis(diphenylphosphine)nickel dichloride
• DPPE.NiCl2
• Dichloro-1,2-bis(diphenylphosphino)ethanenickel(II)
• Dichloro[1,2-bis(diphenylphosphino)ethane]nickel
• Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)
• Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P′]nickel
• Dichloro[1,2-ethanediylbis[diphenylphosphine]]nickel
• Dichloro[ethylenebis[diphenylphosphine]]nickel
• Dichlorobis[(diphenylphosphino)ethane]nickel(II)
• Nickel 1,2-Bis(diphenylphosphino)ethane dichloride
• Nickel, dichloro[1,2-ethanediylbis[diphenylphosphine-κP]]-, (SP-4-2)-
• Nickel, dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P′]-, (SP-4-2)-
• Nickel, dichloro[ethylenebis[diphenylphosphine]]-
• Nickel, dichloro[ethylenebis[diphenylphosphine]]-, cis-
• Phosphine, 1,2-ethanediylbis[diphenyl-, nickel complex
• [1,2-Bis(Diphenylphosphino)Ethane]Dichloronickel(Ii)
• [1,2-Bis(diphenylphosphino)ethane]dichloronickel

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride

CAS: 14647-23-5

Formula: C₂₆H₂₄Cl₂NiP₂

Purity: >96.0%(T)

Color and Shape: Orange to Amber to Dark red powder to crystal

Molecular weight: 528.02

Ref: 3B-B2225

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%

CAS: 14647-23-5

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols

Formula: C₂₆H₂₄Cl₂NiP₂

Purity: 98%

Color and Shape: Orange-red to brown, Powder

Molecular weight: 528.02

Ref: 02-013932

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

CAS: 14647-23-5

Formula: C₂₆H₂₄Cl₂NiP₂

Purity: 98%

Color and Shape: Solid

Molecular weight: 528.0157

Ref: IN-DA0032KC

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

CAS: 14647-23-5

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

Purity: 98%

Molecular weight: 528.02g/mol

Ref: 54-IN10319

[Bis(diphenylphosphino)ethane]dichloronickel

Controlled Product

CAS: 14647-23-5

Applications [Bis(diphenylphosphino)ethane]dichloronickel is a coordination complex with potential antitumor activity. It is also used as a fast and efficient hydrogen production catalyst.
References Mirabelli, C.K., et al.: J. Med. Chem., 30, 2181 (1987); Gan, L., et al.: J. Am. Chem. Soc., 137, 1109 (2015)

Formula: C₂₆H₂₄Cl₂NiP₂

Color and Shape: Neat

Molecular weight: 528.02

Ref: TR-B430455

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

CAS: 14647-23-5

Formula: C₂₆H₂₄Cl₂NiP₂

Purity: 96%

Color and Shape: Solid, Yellow red - deep yellow red powder

Molecular weight: 526.008

Ref: 10-F077791

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride, 99%

CAS: 14647-23-5

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride, 99%

Formula: (C₆H₅)₂PCH₂CH₂P(C₆H₅)₂NiCl₂

Purity: 99%

Color and Shape: orange xtl.

Molecular weight: 528.04

Ref: 08-28-0030

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride

CAS: 14647-23-5

Bis-diphenylphosphinoethane nickel dichloride is a compound that is used for the preparation of other compounds, such as phosphine ligands. Bis-diphenylphosphinoethane nickel dichloride is a solid form of nickel chloride with two crystalline polymorphs, one with a monoclinic crystal structure and the other with a tetragonal crystal structure. In order to obtain the desired product, it must be prepared in an orientational process and synthesised at low temperatures. Bis-diphenylphosphinoethane nickel dichloride has been shown to have anti-cancer properties.br>br> Bis-diphenylphosphinoethane nickel dichloride has also been used to prepare other compounds by cross coupling reactions. This method is effective for preparing compounds that are difficult to make using conventional methods, such as organometallic complexes.br>br> Bis-d

Formula: C₂₆H₂₄Cl₂NiP₂

Purity: Min. 95%

Molecular weight: 528.02 g/mol

Ref: 3D-FB60935