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CAS 14871-41-1

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Carbonylbis(triphenylphosphine)iridium(I)chloride

Description:
Carbonylbis(triphenylphosphine)iridium(I)chloride, with the CAS number 14871-41-1, is a coordination compound featuring iridium in a low oxidation state. This complex is characterized by the presence of a carbonyl group (CO) and two triphenylphosphine ligands (PPh3), which contribute to its stability and reactivity. The iridium center typically exhibits a square planar geometry, a common arrangement for d8 metal complexes, which enhances its catalytic properties. The chloride ion serves as a counterion, influencing the solubility and reactivity of the compound. This iridium complex is notable for its applications in catalysis, particularly in organic synthesis and hydrogenation reactions, due to its ability to facilitate the transfer of electrons. Additionally, the presence of the triphenylphosphine ligands can modulate the electronic properties of the iridium center, making it a versatile catalyst in various chemical transformations. Overall, Carbonylbis(triphenylphosphine)iridium(I)chloride is an important compound in coordination chemistry and catalysis.
Formula:C37H30ClIrOP2
InChI:InChI=1/2C18H15P.CO.ClH.Ir/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h2*1-15H;;1H;/p-1
InChI key:InChIKey=CTCCWDNFEUFLCM-UHFFFAOYSA-M
SMILES:[P]([Ir+]([P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)(C#O)[Cl-])(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6
Synonyms:
  • Bis(triphenylphosphine)carbonylchloroiridium
  • Bis(triphenylphosphine)carbonyliridium chloride
  • Bis(triphenylphosphine)chlorocarbonyliridium(I)
  • Bis(triphenylphosphine)iridiumcarbonyl chloride
  • Carbon Monoxide, Iridium, Triphenylphosphane, Chloride
  • Carbonylbis(triphenylphosphine)iridium chloride
  • Carbonylchlorobis(triphenylphosphine)iridium
  • Chlorocarbonylbis(triphenylphosphine)iridium
  • Chlorocarbonylbis(triphenylphosphine)iridium(I)
  • Iridium, carbonylchlorobis(triphenylphosphine)-
  • See more synonyms
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