CAS 14874-82-9

Dicarbonylrhodium acetylacetonate

Description:

Dicarbonylrhodium acetylacetonate, with the CAS number 14874-82-9, is a coordination complex of rhodium that features two carbonyl (CO) ligands and an acetylacetonate (acac) ligand. This compound is characterized by its distinctive coordination geometry, typically exhibiting a square planar arrangement around the rhodium center. The presence of carbonyl groups contributes to its stability and reactivity, making it a valuable precursor in various catalytic processes, particularly in organic synthesis and homogeneous catalysis. Dicarbonylrhodium acetylacetonate is often utilized in reactions involving C-H activation and carbon-carbon bond formation. It is generally soluble in organic solvents, which enhances its applicability in synthetic chemistry. Additionally, this compound is known for its ability to facilitate the transfer of rhodium in catalytic cycles, thereby playing a crucial role in the development of efficient catalytic systems. Safety precautions should be observed when handling this compound, as it may pose health risks if inhaled or ingested.

Formula: C₇H₇O₄Rh

InChI: InChI=1/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;/rC5H7O2Rh.2CO/c1-4-3-5(2)7-8-6-4;2*1-2/h3H,1-2H3;;

InChI key: InChIKey=QKXHARLOMLGJCF-UHFFFAOYSA-N

SMILES: C(#O)[Rh+]1(C#O)O=C(C)[CH-]C(C)=O1

Synonyms:

• (Acetylacetonate)dicarbonylrhodium
• (Acetylacetonato)dicarbonyl rhodium
• (Acetylacetonato)dicarbonylrhodium(I)
• (SP-4-2)-Dicarbonyl(2,4-pentanedionato-κO²,κO⁴)rhodium
• Acetylacetonatobis(carbonyl)rhodium
• Acetylacetonatodicarbonyl rhodium
• Acetylacetonatodicarbonylrhodium(I)
• Acetylacetonatorhodium dicarbonyl
• Acetylacetonatorhodium(I) dicarbonyl
• Carbon Monoxide
• Dicarbonyl(2,4-pentanedionato)rhodium
• Dicarbonyl(2,4-pentanedionato)rhodium(Ⅰ)
• Dicarbonyl(2,4-pentanedionato-κO,κO')rhodium
• Dicarbonyl(pentan-2,4-dionato-O,O')rhodium
• Dicarbonylacetylacetonato rhodium(I)
• Dicarbonylacetylacetonatorhodium
• Dicarbonylacetylacetonatorhodium(I)
• Dicarbonylrhodium acetylacetonate
• Dicarbonylrhodium(I) acetylacetonate
• Rh(CO)₂(acac)
• Rh(acac)(CO)₂
• Rhodium acetylacetonate dicarbonyl
• Rhodium biscarbonyl acetylacetonate
• Rhodium dicarbonylacetylacetonate
• Rhodium i dicarbonyl 2,4-pentanedionate
• Rhodium, (2,4-pentanedionato)dicarbonyl-
• Rhodium, dicarbonyl(2,4-pentanedionato)-
• Rhodium, dicarbonyl(2,4-pentanedionato-O,O')-, (SP-4-2)-
• Rhodium, dicarbonyl(2,4-pentanedionato-κO,κO')-, (SP-4-2)-
• Rhodium, dicarbonyl(2,4-pentanedionato-κO2,κO4)-, (SP-4-2)-
• Rhodium, dicarbonyl(2,4-pentanedionato-κO²,κO⁴)-, (SP-4-2)-
• dicarbonil(pentano-2,4-dionato-O,O')rodio
• dicarbonyl(pentane-2,4-dionato-O,O')rhodium
• icarbonyl(2,4-pentanedionato)rhodium(I)
• Dicarbonylacetylacet
• Acetylacetonatodicarbonylrhodium(I) Dichroic green-red crystals sublm. 144-147
• (Acetylacetonato)dicarbonylrhodium (I), min. 99% (Rh-50, #209050)
• Rhodium, dicarbonyl(2,4-pentanedionato-O,O')-
• dicarbonyl-2,4-pentanedionatorhodium(i)
• Acetylacetonatorhodium(I) dicarbonyl~Dicarbonyl(2,4-pentanedionato)rhodium(I)
• (Actylacetatonato) dicarbonylrhodium (I)
• Dicarbonyl-acetylacetonato-rhodium(I), Dicarbonylrhodium(I) 2,4-pentanedionate, Rhodium(I) dicarbonyl acetylacetonate
• Dicarbonylrhodium(I) 2,4-pentanedionate, Rhodium(I) dicarbonyl acetylacetonate
• Dicarbonylacetylacetonatorhodium(I),99%
• Acetylacetonatodicarbonylrhodium
• (Acetylacetonato)dicarbonylrhodiuM(Ⅰ), 40% Rh, Product of UMicore
• Dicarbonylacetylacetonato rhodiuM(I),98%
• Dicarbonyl-(2,4-pentandione)-rhodium
• (ACETYLACETONATO)DICARBONYLRHODIUM(I), 9 8%
• RHODIUM DICARBONYL-2,4-PENTANEDIONATE
• (Acetylacetonate group) two carbon-based iridiuM (I)
• 2,4-Pentanedionatodicarbonyl rhodium
• RHODIUM(I) DICARBONYL ACETYLACETONATE

Dicarbonyl(2,4-pentanedionato)rhodium(I), 97%

CAS: 14874-82-9

(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and redu

Formula: C₇H₇O₄Rh

Purity: 97%

Color and Shape: Green, Crystalline powder or powder

Molecular weight: 258.03

Ref: 02-039295

Dicarbonylacetylacetonato rhodium(I), 99%

CAS: 14874-82-9

Dicarbonylacetylacetonato rhodium(I), 99%

Formula: Rh(CO)₂(C₅H₇O₂)

Purity: 99%

Color and Shape: greenish-red xtl.

Molecular weight: 258.04

Ref: 08-45-0700

Dicarbonylacetylacetonato rhodium(I)

CAS: 14874-82-9

Formula: C₇H₈O₄Rh

Purity: 98%

Color and Shape: Solid

Molecular weight: 259.0415

Ref: IN-DA003BZB

Dicarbonylacetylacetonato Rhodium(I)

CAS: 14874-82-9

Dicarbonylacetylacetonato Rhodium(I)

Purity: 98%,Rh:39%

Molecular weight: 259.04g/mol

Ref: 54-IN10429

Dicarbonylrhodium(I) 2,4-pentanedionate (CARAC); 99.95% (metals basis)

CAS: 14874-82-9

Formula: Rh(CO)₂(C₅H₇O₂)

Molecular weight: 258.04

Ref: 7W-GX9796

(Acetylacetonato)dicarbonylrhodium(I)

Controlled Product

CAS: 14874-82-9

Applications (Acetylacetonato)dicarbonylrhodium(I) involved in the preparation of rhodium chelating bisphosphate brigaded complex and use as hydroformylation catalysts.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Bondzic. B.P., et al.: J. Mol. Catal. A: Chem., 423, 472-477 (2016)

Formula: C₇H₇O₄Rh

Color and Shape: Neat

Molecular weight: 258.03

Ref: TR-A168710

Dicarbonylacetylacetonato rhodium(I)

CAS: 14874-82-9

Formula: C₇H₇O₄Rh

Purity: 95.0%

Molecular weight: 258.035

Ref: 10-F379058