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CAS 14973-89-8

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Bromotris(triphenylphosphine)rhodium

Description:
Bromotris(triphenylphosphine)rhodium, with the CAS number 14973-89-8, is a coordination complex of rhodium that features bromine and triphenylphosphine ligands. This compound is characterized by its distinctive coordination geometry, typically exhibiting a square planar arrangement around the rhodium center. The presence of triphenylphosphine ligands contributes to its stability and solubility in organic solvents, making it useful in various catalytic applications, particularly in organic synthesis and homogeneous catalysis. The bromine atom serves as a leaving group, facilitating reactions such as C-H activation and cross-coupling processes. Additionally, this complex is known for its role in facilitating the formation of carbon-carbon bonds, showcasing its utility in the development of complex organic molecules. Its reactivity and selectivity can be influenced by the nature of the substrates and reaction conditions, making it a valuable tool in synthetic chemistry. Overall, bromotris(triphenylphosphine)rhodium is an important compound in the field of organometallic chemistry and catalysis.
Formula:C54H45BrP3Rh
InChI:InChI=1S/3C18H15P.BrH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChI key:InChIKey=NCOJWJLEQUCXMV-UHFFFAOYSA-M
SMILES:[Rh+]([P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)([P](C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6)([P](C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9)[Br-]
Synonyms:
  • (SP-4-2)-Bromotris(triphenylphosphine)rhodium
  • Bromotris(triphenylphosphine)rhodium
  • Phosphine, Triphenyl-, Bromide, Rhodium Salt (3:1)
  • Rhodium tris(triphenylphosphine) bromide
  • Rhodium, bromotris(triphenylphosphine)-
  • Rhodium, bromotris(triphenylphosphine)-, (SP-4-2)-
  • Tris(triphenylphosphine)bromide
  • Tris(triphenylphosphine)bromorhodium
  • Tris(triphenylphosphine)rhodium bromide
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