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CAS 154090-43-4

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Rhodium, tetrakis[μ-[α-(1,1-dimethylethyl)-1,3-dihydro-1,3-dioxo-2H-isoindole-2-acetato-κO2:κO2′]]di-, (Rh-Rh), stereoisomer

Description:
Rhodium, tetrakis[μ-[α-(1,1-dimethylethyl)-1,3-dihydro-1,3-dioxo-2H-isoindole-2-acetato-κO2:κO2′]]di-, (Rh-Rh) is a coordination compound featuring rhodium as the central metal ion, coordinated with a complex organic ligand. The compound is characterized by its tetrakis structure, indicating the presence of four identical ligand units that bridge between two rhodium centers, forming a dinuclear complex. The ligands are derived from an isoindole framework, which contributes to the compound's unique properties, including potential catalytic activity and stability. The presence of bulky tert-butyl groups in the ligand enhances steric hindrance, influencing the compound's reactivity and solubility. This compound may exhibit interesting electronic properties due to the metal-ligand interactions, making it a subject of interest in fields such as organometallic chemistry and catalysis. Its specific stereochemistry can affect its biological activity and interaction with other molecules, which is crucial for applications in medicinal chemistry and materials science.
Formula:C56H56N4O16Rh2
InChI:InChI=1S/4C14H15NO4.2Rh/c4*1-14(2,3)10(13(18)19)15-11(16)8-6-4-5-7-9(8)12(15)17;;/h4*4-7,10H,1-3H3,(H,18,19);;/q;;;;2*+2/p-4/t4*10-;;/m1111../s1
InChI key:InChIKey=PDTSLZCQKKXVQL-MYHKTDPMSA-J
SMILES:[C@H]([C@@](C)(C)C)(C=1[O-][Rh+2]234[Rh+2]([O-]C([C@H](C(C)(C)C)N5C(=O)C=6C(C5=O)=CC=CC6)=O2)([O-]C([C@H]([C@@](C)(C)C)N7C(=O)C=8C(C7=O)=CC=CC8)=O3)(O=C([C@H](C(C)(C)C)N9C(=O)C=%10C(C9=O)=CC=CC%10)[O-]4)O1)N%11C(=O)C=%12C(C%11=O)=CC=CC%12
Synonyms:
  • Rh2[(S)-pttl]4
  • Tetrakis[μ-(2S)-3,3-dimethyl-2-(phthalimido)butanoato-κO,O]dirhodium
  • Rhodium, tetrakis[μ-[α-(1,1-dimethylethyl)-1,3-dihydro-1,3-dioxo-2H-isoindole-2-acetato-Oα:Oα′]]di-, (Rh-Rh), stereoisomer
  • Rh2(S-PTTL)4
  • Rhodium, tetrakis[μ-[α-(1,1-dimethylethyl)-1,3-dihydro-1,3-dioxo-2H-isoindole-2-acetato-κO2:κO2′]]di-, (Rh-Rh), stereoisomer
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