CAS 155806-35-2: (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl] ethyldicyclohexylphosphine
Description:(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine, with CAS number 155806-35-2, is a chiral phosphine ligand commonly used in asymmetric synthesis and catalysis. This compound features a ferrocenyl moiety, which contributes to its stability and electronic properties, making it effective in facilitating various chemical reactions. The presence of diphenylphosphino groups enhances its coordination capabilities with transition metals, allowing it to form stable complexes that are crucial in catalyzing reactions such as cross-coupling and hydrogenation. The dicyclohexylphosphine component provides steric bulk, which can influence the selectivity and reactivity of the metal-ligand complex. Its chirality is significant for applications in asymmetric synthesis, where the control of stereochemistry is essential. Overall, this ligand exemplifies the importance of phosphine ligands in modern organometallic chemistry and catalysis, showcasing unique properties that enable efficient and selective transformations in synthetic organic chemistry.
Formula:C36H44FeP2
InChI:InChI=1/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h4-5,10-14,19-27H,2-3,6-9,15-18H2,1H3;1-5H;/t25-;;/m1../s1
- Synonyms:
- (R)1[(1S)2(diphenylphosphino)ferrocenyl] et-dicyclohexylphos
- (R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine
- Josiphos SLJ001-1
- 1,2,3,4,5-cyclopentanepentayl, compd. with 1-[(1R)-1-(dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
- (R)-(S)-Josiphos
- (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct
- (R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine
Ref: 3B-D5417
250mg | 132.00 € |

Ferrocene, 1-[(1R)-1-(dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)-, (2R)-
Ref: IN-DA001O89
1g | 54.00 € | ||
5g | 135.00 € | ||
10g | 186.00 € | ||
15g | 270.00 € | ||
25g | 478.00 € | ||
100mg | 21.00 € | ||
250mg | 28.00 € |

(R)-1-[(Sp)-2-(Diphenylphosphino)ferrocenyl]ethyl dicyclohexylphosphine
Ref: 10-F996227
1g | 36.00 € | ||
5g | 160.00 € | ||
10g | 265.00 € | ||
100mg | 10.00 € | ||
250mg | 16.00 € |

(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine, 97+%
Ref: AC-37067
100mg | To inquire | ||
500mg | To inquire |

(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine
Ref: 54-OR54583
1g | 157.00 € | ||
250mg | 111.00 € |

(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct, min. 97% (R)-(S)-JOSIPHOS
Ref: 08-26-1210
2g | 1,254.00 € | ||
10g | 4,694.00 € | ||
100mg | 141.00 € | ||
500mg | 468.00 € |

(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine
Ref: 3D-FD166794
2g | 343.00 € | ||
5g | 470.00 € |