CAS 15629-92-2

Dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]nickel

Description:

Dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]nickel, with the CAS number 15629-92-2, is a coordination compound featuring a nickel center coordinated to two diphenylphosphine ligands and two chloride ions. This compound is characterized by its bidentate phosphine ligands, which enhance its stability and reactivity. The presence of the 1,3-propanediyl linker provides a unique structural framework that influences the spatial arrangement of the ligands around the nickel atom. Typically, nickel complexes like this one exhibit a square planar geometry, which is common for nickel(II) complexes. The diphenylphosphine ligands contribute to the electronic properties of the complex, potentially making it useful in catalysis and organic synthesis. Additionally, the compound's solubility and reactivity can vary depending on the solvent and conditions, making it a subject of interest in coordination chemistry and materials science. Safety precautions should be taken when handling this compound, as it may pose health risks typical of organophosphorus compounds.

Formula: C₂₇H₂₆Cl₂NiP₂

InChI: InChI=1/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

InChI key: InChIKey=ZBQUMMFUJLOTQC-UHFFFAOYSA-L

SMILES: [Cl-][Ni+2]1([Cl-])[P](CCC[P]1(C2=CC=CC=C2)C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5

Synonyms:

• 1,3-Bis(diphenylphosphino)nickel dichloride
• 1,3-Bis(diphenylphosphino)propane dichloronickel
• 1,3-Bis(diphenylphosphino)propane nickel chloride
• 1,3-Bis(diphenylphosphino)propanenickel dichloride
• Bis[1,3-bis(diphenylphosphino)propane]dichloronickel
• DPPP.NiCl2
• Dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]nickel
• Dichloro[1,3-Bis-(diphenylphosphino)propane] nickel(Ⅱ)
• Dichloro[1,3-bis(diphenylphosphino)propane]nickel
• Dichloronickel-Propane-1,3-Diylbis(Diphenylphosphane) (1:1)
• Nickel 1,3-bis(diphenylphosphino)propane dichloride
• Nickel, dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]-
• Nickel, dichloro[1,3-propanediylbis[diphenylphosphine-κP]]-
• Nickel, dichloro[1,3-propanediylbis[diphenylphosphine]-P,P′]-
• Nickel, dichloro[trimethylenebis[diphenylphosphine]]-
• Phosphine, 1,3-propanediylbis[diphenyl-, nickel complex
• [1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
• [1,3-Bis(diphenylphosphino)propane]nickel(II)Dichloride
• [Bis(diphenylphosphino)propane]nickel dichloride
• 1,3-Bis(diphenylphosphino)propane nickel(II) chloride
• 1,3-Bis(Diphenylphosphino)Propane nickel(II)Chloride
• 1,3-bis(diphenylphosphino)propane nickel ii chloride
• 1,3-BIS(DIPHENYLPHOSPHINE)PROPANE NICKEL(II) CHLORIDE
• NiCl2(DPPP)NiCl2(DPPP)
• Dichloro[1,3-Bis-(Diphenylphos
• NICL2(DPPP)/ 1,3-BIS(DIPHENY PHOSPHINE) PROPANE NICKEL(II)CHLORIDE
• DICHLORO[1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE] NICKE
• 1,3-Bis(dipenylphosphino)propanenickel(II) chloride
• 1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride
• Dichlorobis(1,3-diphenylphosphino)propaneünickel(II), C 59.9%
• 1,3-BIS-(DIPHENYLPHOSPHINO)-PROPAN-
• 1,3-Bis(diphenylphosphino)propanenickel(II)chloride,99%
• 1.3-Bis(dipheny phosphine) propane nickel(II)chloride
• (1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride

CAS: 15629-92-2

Formula: C₂₇H₂₆Cl₂NiP₂

Purity: >98.0%(T)

Color and Shape: Orange to Brown to Dark red powder to crystal

Molecular weight: 542.05

Ref: 3B-B1313

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)

CAS: 15629-92-2

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythi

Formula: C₂₇H₂₆Cl₂NiP₂

Color and Shape: Orange to red, powder

Molecular weight: 542.04

Ref: 02-030167

1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99%

CAS: 15629-92-2

1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99%

Formula: (C₆H₅)₂PCH₂CH₂CH₂P(C₆H₅)₂NiCl₂

Purity: 99%

Color and Shape: red xtl.

Molecular weight: 542.08

Ref: 08-28-0080

1,3-Bis(diphenylphosphino)propane nickel(II)chloride

CAS: 15629-92-2

Formula: C₂₇H₂₆Cl₂NiP₂

Purity: 98%

Color and Shape: Solid

Molecular weight: 542.0423

Ref: IN-DA0032I0

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

CAS: 15629-92-2

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

Formula: Cl₂Ni·C₂₇H₂₆P₂

Purity: 98%

Color and Shape: red solid

Molecular weight: 542.04g/mol

Ref: 54-OR70169

1,3-Bis(diphenylphosphino)propane-nickel (II) chloride

CAS: 15629-92-2

Formula: C₂₇H₂₆Cl₂NiP₂

Molecular weight: 542.03

Ref: 7W-GK3219

1,3-Bis(diphenylphosphino)propanedichloronickel II

CAS: 15629-92-2

Formula: C₂₇H₂₆Cl₂NiP₂

Purity: 95%

Color and Shape: Solid

Molecular weight: 540.024

Ref: 10-F044623

[1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride

Controlled Product

CAS: 15629-92-2

Applications [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins.
References Li, J., et al.: J. Polym. Res., 19, 1-9 (2012); Yamamoto, T., et al.: Tetrahedron Lett., 42, 8653-8656 (2001);

Formula: C₂₇H₂₆Cl₂NiP₂

Color and Shape: Neat

Molecular weight: 542.04

Ref: TR-B430353