CAS 157282-19-4

Diadamantylchlorophosphine

Description:

Diadamantylchlorophosphine is a chemical compound characterized by its unique structure, which includes two adamantyl groups attached to a phosphorus atom, along with a chlorine substituent. This compound belongs to the class of organophosphorus compounds, which are known for their diverse applications in organic synthesis and as intermediates in the production of various chemicals. Diadamantylchlorophosphine is typically a colorless to pale yellow liquid or solid, depending on its specific form and purity. It exhibits properties such as high thermal stability and reactivity due to the presence of the phosphorus-chlorine bond, making it useful in various chemical reactions, including nucleophilic substitutions. Additionally, the adamantyl groups contribute to its steric bulk, influencing its reactivity and solubility in organic solvents. Safety precautions are essential when handling this compound, as it may pose health risks if inhaled or ingested. Overall, Diadamantylchlorophosphine is a notable compound in the field of organophosphorus chemistry, with potential applications in materials science and pharmaceuticals.

Formula: C₂₀H₃₀ClP

InChI: InChI=1S/C20H30ClP/c21-22(19-7-13-1-14(8-19)3-15(2-13)9-19)20-10-16-4-17(11-20)6-18(5-16)12-20/h13-18H,1-12H2

InChI key: InChIKey=BVOJCPQWSXCCKU-UHFFFAOYSA-N

SMILES: P(Cl)(C12CC3CC(C1)CC(C2)C3)C45CC6CC(C4)CC(C5)C6

Synonyms:

• P,P-Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphinous chloride
• Diadamantylchlorophosphine
• Bis(1-adamantyl)phosphinous chloride
• Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl)-
• Phosphinous chloride, bis(tricyclo[3.3.1.13,7]dec-1-yl)-

bis(adamantan-1-yl)(chloro)phosphane

CAS: 157282-19-4

Formula: C₂₀H₃₀ClP

Purity: 95%

Color and Shape: Solid

Molecular weight: 336.8790

Ref: IN-DA001PC2

Di(1-adamantyl)chlorophosphine

CAS: 157282-19-4

Di(1-adamantyl)chlorophosphine

Purity: 97%

Molecular weight: 336.88g/mol

Ref: 54-OR53150

Di-1-adamantylchlorophosphine, min. 97%

CAS: 157282-19-4

Di-1-adamantylchlorophosphine, min. 97%

Formula: (C₁₀H₁₅)₂ClP

Purity: min. 97%

Color and Shape: white solid

Molecular weight: 336.88

Ref: 08-15-1095

Di(1-adamantyl)chlorophosphine

CAS: 157282-19-4

Di(1-adamantyl)chlorophosphine is a bifunctional ligand that can be used for the palladium-catalyzed coupling of aryl chlorides and amines. Di(1-adamantyl)chlorophosphine is synthesized from adamantane, phosphorous pentachloride, and anhydrous ammonia in the presence of catalytic amounts of palladium. Di(1-adamantyl)chlorophosphine is immobilized on silica gel to prevent hydrolysis. This ligand reacts with primary amines to form iminophosphoranes, which can then be reacted with aryl chlorides to form aryl chloroamines.

Formula: C₂₀H₃₀ClP

Purity: Min. 95%

Molecular weight: 336.88 g/mol

Ref: 3D-HGA28219