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CAS 15746-57-3

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cis-Bis(2,2'-bipyridyl)ruthenium(II) chloride dihydrate

Description:
Cis-Bis(2,2'-bipyridyl)ruthenium(II) chloride dihydrate, commonly referred to as Ru(bpy)₂Cl₂·2H₂O, is a coordination complex featuring ruthenium as the central metal ion coordinated to two 2,2'-bipyridine ligands and two chloride ions. This compound is characterized by its distinctive cis configuration, which influences its electronic and optical properties. It typically appears as a red to purple crystalline solid and is soluble in polar solvents such as water and methanol. The complex exhibits interesting photophysical properties, including strong absorption in the visible region and luminescence, making it valuable in photochemical applications, such as solar energy conversion and as a probe in biological systems. Additionally, it can participate in various redox reactions, showcasing its potential in catalysis and electrochemistry. The dihydrate form indicates the presence of two water molecules of crystallization, which can affect its stability and solubility. Overall, Ru(bpy)₂Cl₂·2H₂O is a significant compound in coordination chemistry with diverse applications in materials science and biochemistry.
Formula:C20H20Cl2N4O2Ru
InChI:InChI=1/C10H18N2.C10H14N2.2ClH.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;/h9-10H,1-8H2;1,3,5,10H,2,4,6-8H2;2*1H;/q2*-2;;;+2/p-2
SMILES:C1CC[N-]C(C1)C1CCCC[N-]1.C1=CC[N-]C(=C1)C1CCCC[N-]1.Cl.Cl.[Ru]
Synonyms:
  • cis-Dichloro(2,2-bipyridine)ruthenium(II) dihydrate
  • cis-Dichlorobis(2,2-bipyridine)ruthenium(II) dihydrate
  • Dichlororuthenium
  • 2-Piperidin-1-Id-2-Ylpiperidin-1-Ide
  • 2-piperidin-1-id-2-yl-6H-pyridin-1-ide
  • cis-Bis(2,2-bipyridyl)ruthenium(II) chloride dihydrate
  • Di(2,2'-bipyridine)ruthenium dichloride
  • Bis(2,2'-bipyridine)ruthenium dichloride
  • Bis(2,2'-bipyridine)dichlororuthenium
  • -bipyridyl)ruthenium(II) chloride dihydrate
  • See more synonyms
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