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CAS 16456-81-8

:

5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

Description:
5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride, commonly referred to as iron(III) tetraphenylporphyrin chloride, is a coordination compound characterized by its porphyrin structure, which consists of a cyclic arrangement of carbon and nitrogen atoms. The presence of iron in the porphyrin core imparts unique electronic and magnetic properties, making it a valuable compound in various applications, including catalysis and as a model for heme proteins. This compound typically exhibits a deep color, often appearing as a dark purple or red solution, due to its strong light-absorbing properties. It is soluble in organic solvents like chloroform and dichloromethane but has limited solubility in water. The iron(III) ion in the complex can participate in redox reactions, enhancing its utility in chemical transformations. Additionally, the tetraphenyl substituents contribute to the compound's stability and solubility, while also influencing its electronic properties. Overall, this compound serves as an important tool in both synthetic and analytical chemistry.
Formula:C44H28ClFeN4
InChI:InChI=1/C44H28N4.ClH.Fe/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,42-35-,43-38-,44-40-;;/rC44H28ClFeN4/c45-46-47-33-21-23-35(47)42(30-15-7-2-8-16-30)37-25-27-39(49(37)46)44(32-19-11-4-12-20-32)40-28-26-38(50(40)46)43(31-17-9-3-10-18-31)36-24-22-34(48(36)46)41(33)29-13-5-1-6-14-29/h1-28H
SMILES:c1ccc(cc1)C1=c2ccc(=C(c3ccccc3)C3=NC(=C(c4ccccc4)c4ccc(C(=C5C=CC1=N5)c1ccccc1)[n-]4)C=C3)[n-]2.Cl.[Fe]
Synonyms:
  • 5,10,15,20-Tetraphenyl-21H,23H-Porphyrin Iron(Iii) Chloride
  • Meso-Tetraphenylporphyrin Iron(Iii) Chloride
  • Meso-Tetraphenylporphyrin Iron(Iii) Chloride Complex
  • Iron Tpp
  • Iron (Iii) Meso-Tetraphenylporphine Chloride
  • Iron (Iii) Tetraphenylporphine Chloride
  • Rarechem As Sa 0004
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