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CAS 164594-13-2

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PHENYL[2-(TRIMETHYLSILYL)PHENYL]IODONIUM TRIFLATE

Description:
Phenyl[2-(trimethylsilyl)phenyl]iodonium triflate is an organoiodine compound characterized by its iodonium cation, which is a positively charged species containing iodine. This compound features a phenyl group and a trimethylsilyl-substituted phenyl group, contributing to its unique reactivity and stability. The triflate anion, derived from trifluoromethanesulfonic acid, enhances the solubility and reactivity of the iodonium salt in various organic solvents. This compound is often utilized in photochemical and electrophilic reactions, serving as a powerful electrophile in synthetic organic chemistry. Its ability to generate reactive intermediates upon decomposition makes it valuable in processes such as polymerization and the synthesis of complex organic molecules. Additionally, the presence of the trimethylsilyl group can influence the electronic properties and steric hindrance, affecting the overall reactivity of the compound. Overall, phenyl[2-(trimethylsilyl)phenyl]iodonium triflate is a versatile reagent with significant applications in advanced organic synthesis.
Formula:C16H18F3IO3SSi
InChI:InChI=1/C16H18F3IO3SSi/c1-25(2,3)15-12-8-7-11-14(15)20(13-9-5-4-6-10-13)23-24(21,22)16(17,18)19/h4-12H,1-3H3
SMILES:C[Si](C)(C)c1ccccc1I(c1ccccc1)OS(=O)(=O)C(F)(F)F
Synonyms:
  • Phenyl[2-(Trimethylsilyl)Phenyl]Iodonium Trifluoromethanesulfonate
  • Phenyl{[(Trifluoromethyl)Sulfonyl]Oxy}[2-(Trimethylsilyl)Phenyl]-Λ3-Iodane
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