CAS 16687-12-0
:Trimethylsilylperrhenate
Description:
Trimethylsilylperrhenate is an organosilicon compound characterized by the presence of a perrhenate ion (ReO4-) bonded to a trimethylsilyl group (Si(CH3)3). This compound typically appears as a colorless to pale yellow solid and is known for its stability under ambient conditions. It is soluble in organic solvents, which makes it useful in various chemical applications, particularly in organic synthesis and catalysis. The trimethylsilyl group enhances the compound's volatility and reactivity, allowing it to participate in a range of chemical reactions, including nucleophilic substitutions and coupling reactions. Additionally, trimethylsilylperrhenate can serve as a precursor for the synthesis of other rhenium-containing compounds. Its unique properties stem from the combination of the perrhenate anion's strong oxidizing capabilities and the steric and electronic effects of the trimethylsilyl group. Safety precautions should be taken when handling this compound, as it may pose health risks if ingested or inhaled.
Formula:C3H9O4ReSi
InChI:InChI=1/C3H9OSi.3O.Re/c1-5(2,3)4;;;;/h1-3H3;;;;/q-1;;;;+1/rC3H9O4ReSi/c1-9(2,3)7-8(4,5)6/h1-3H3
SMILES:C[Si](C)(C)[O-].O.O.O.[Re]
Synonyms:- Trioxo(Trimethylsilanolato)Rhenium
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