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CAS 167416-28-6

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(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine

Description:
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine is a chiral organophosphorus compound notable for its application in asymmetric synthesis and catalysis. This compound features a ferrocenyl moiety, which contributes to its stability and unique electronic properties, making it a valuable ligand in coordination chemistry. The presence of dicyclohexylphosphino groups enhances its steric and electronic characteristics, allowing it to effectively stabilize metal centers in catalytic processes. The chirality of the compound is significant, as it can influence the selectivity of reactions, particularly in enantioselective catalysis. Additionally, the bulky dicyclohexyl groups provide steric hindrance, which can affect the reactivity and selectivity of the metal-ligand complex. This compound is typically handled with care due to the potential toxicity associated with organophosphorus compounds. Its applications extend to fields such as organic synthesis, materials science, and medicinal chemistry, where it can facilitate the formation of complex organic molecules with high precision.
Formula:C36H56FeP2
InChI:InChI=1/C31H51P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h14,23-29H,2-13,15-22H2,1H3;1-5H;/t25-;;/m1../s1
SMILES:C[C@H](C1C=CC=C1P(C1CCCCC1)C1CCCCC1)P(C1CCCCC1)C1CCCCC1.C1=C[CH]C=C1.[Fe]
Synonyms:
  • (R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-dicyclohexylphos
  • (R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
  • Josiphos SLJ003-1
  • 1,2,3,4,5-cyclopentanepentayl, compd. with 1-(dicyclohexylphosphino)-2-[(1R)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
  • (R)-(-)-1-[(S)-2-Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
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