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CAS 17185-29-4

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Carbonylhydridotris(triphenylphosphine)rhodium

Description:
Carbonylhydridotris(triphenylphosphine)rhodium, often referred to as Rh(CO)(H)(PPh₃)₃, is a coordination complex of rhodium featuring a carbonyl group, a hydride, and three triphenylphosphine ligands. This compound is characterized by its distinctive coordination geometry, typically exhibiting a square planar arrangement around the rhodium center. The presence of the carbonyl and hydride ligands contributes to its reactivity, making it a valuable catalyst in various organic transformations, including hydrogenation and carbonylation reactions. The triphenylphosphine ligands enhance the stability and solubility of the complex in organic solvents. Additionally, this compound is notable for its role in organometallic chemistry and catalysis, where it can facilitate the formation of C-C and C-H bonds. Its properties, such as thermal stability and reactivity, can be influenced by the nature of the ligands and the reaction conditions. Overall, Carbonylhydridotris(triphenylphosphine)rhodium is an important compound in synthetic chemistry, particularly in the development of catalytic processes.
Formula:C55H46OP3Rh
InChI:InChI=1S/3C18H15P.CO.Rh.H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;;
InChI key:InChIKey=AACIZACVKFEETJ-UHFFFAOYSA-N
SMILES:[Rh+]([P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)([P](C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6)([P](C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9)(C#O)[H-]
Synonyms:
  • $L1-Rhodane, Triphenylphosphane
  • (TB-5-23)-Carbonylhydrotris(triphenylphosphine)rhodium
  • Carbon Monoxide
  • Carbonyl hydridotris(triphenylphosphine) rhodium
  • Carbonylhydridotris(triphenylphosphine)rhodium
  • Carbonylhydridotris(triphenylphosphine)rhodium(Ⅰ)
  • Carbonylhydrotris(triphenylphosphine)rhodium
  • Carbonyltris(triphenylphosphine)rhodium(I)hydride
  • Hydridocarbonyltris(triphenylphosphine)rhodium
  • Hydridocarbonyltris(triphenylphosphine)rhodium(I)
  • See more synonyms
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