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CAS 17250-25-8

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Carbonylhydrotris(triphenylphosphine)iridium

Description:
Carbonylhydrotris(triphenylphosphine)iridium, with the CAS number 17250-25-8, is a coordination complex of iridium featuring a carbonyl group and three triphenylphosphine ligands. This compound typically exhibits a square planar geometry around the iridium center, which is characteristic of many d8 metal complexes. The presence of the carbonyl group contributes to its reactivity and stability, while the triphenylphosphine ligands enhance solubility and facilitate various chemical interactions. It is often used in catalysis, particularly in organic synthesis and hydrogenation reactions, due to its ability to activate substrates and facilitate electron transfer processes. The compound is sensitive to air and moisture, necessitating careful handling and storage under inert atmospheres. Its unique electronic properties and steric bulk from the triphenylphosphine ligands make it a valuable species in organometallic chemistry and catalysis research.
Formula:C55H45IrOP3
InChI:InChI=1/3C18H15P.CO.Ir/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;/h3*1-15H;;
InChI key:InChIKey=IOPVMNYABUEALT-UHFFFAOYSA-N
SMILES:[Ir+]([P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)([P](C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6)([P](C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9)(C#O)[H-]
Synonyms:
  • Carbon Monoxide
  • Carbonylhydridotris(triphenylphosphine)iridium
  • Carbonylhydridotris(triphenylphosphine)iridium(Ⅰ)
  • Carbonylhydrotris(triphenylphosphine)iridium
  • Hydride
  • HydridocarbonyltristriphenylphosphineiridiumI
  • Hydrocarbonyltris(triphenylphosphine)iridium
  • Iridium, carbonylhydrotris(triphenylphosphine)-
  • Iridium, hydrocarbonyltris(triphenylphosphine)-
  • Iridium,Triphenylphosphane
  • See more synonyms
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