CAS 174467-31-3

(SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene

Description:

(SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene is a chiral bidentate ligand that features a ferrocene backbone, which is a metallocene compound consisting of two cyclopentadienyl anions bound to a central iron cation. This compound is characterized by its unique structural features, including two diphenylphosphino groups that enhance its coordination properties with transition metals, making it valuable in catalysis and asymmetric synthesis. The presence of dimethylamino groups contributes to its solubility and reactivity, while the chiral nature of the ligand allows for the induction of chirality in metal complexes, which is crucial for enantioselective reactions. The specific stereochemistry denoted by (SP,S'P) indicates the spatial arrangement of the substituents, which can influence the ligand's interaction with metal centers. Overall, this compound exemplifies the intersection of organometallic chemistry and asymmetric catalysis, showcasing the importance of ligand design in enhancing catalytic performance.

Synonyms:

• (R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
• (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene

Ferrocene,1,1'-bis[(dimethylamino)phenylmethyl]-2,2'-bis(diphenylphosphino)-,stereoisomer

CAS: 174467-31-3

Formula: C₅₂H₄₇FeN₂P₂

Purity: 98%

Molecular weight: 817.7355

Ref: IN-DA01FL43

(Sp,Sp)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene

CAS: 174467-31-3

(Sp,Sp)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene

Purity: 98%

Molecular weight: 817.75g/mol

Ref: 54-IN12936

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenyl­phosphino)ferrocene, min. 97%

CAS: 174467-31-3

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97%

Formula: C₅₂H₅₀FeN₂P₂

Purity: min. 97%

Color and Shape: yellow to red solid

Molecular weight: 820.76

Ref: 08-26-0252