CAS 176763-62-5: [[2,2′-[(1R,2R)-1,2-Cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]cobalt

Description: The chemical substance with the name "[[2,2′-[(1R,2R)-1,2-Cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]cobalt" and CAS number "176763-62-5" is a cobalt complex characterized by its intricate structure, which includes a cobalt center coordinated to a bidentate ligand system. The ligand features a cyclohexanediyl backbone, which provides a rigid framework, and incorporates nitrilo groups that enhance coordination with the cobalt ion. Additionally, the presence of bulky tert-butyl groups on the phenolic moieties contributes to steric hindrance, influencing the complex's solubility and reactivity. This compound is of interest in coordination chemistry and may exhibit unique catalytic properties or biological activity due to its specific ligand arrangement and metal center. Its stability and reactivity can be influenced by the electronic properties of the ligands and the oxidation state of cobalt, making it a subject of study in various chemical applications, including catalysis and materials science.

Formula: C₃₆H₅₂CoN₂O₂

InChI: InChI=1S/C36H54N2O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;/h17-22,29-30,39-40H,13-16H2,1-12H3;/q;+2/p-2/t29-,30-;/m1./s1

InChI key: InChIKey=ZFWPDJKMASHRPT-GAQUOPITSA-L

SMILES: [O-]1C2=C(C=C(C=C2C(C)(C)C)C(C)(C)C)C=[N]3C4CCCCC4[N]5=CC=6C=C(C=C(C6[O-][Co+2]135)C(C)(C)C)C(C)(C)C

Synonyms:

• (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
• (R,R)-()-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
• (R,R)-(-)-N,N'-Bis(3,5-Di-Tert-Butylsalicylidene)-1,2-Cyclohexanediamino-Cobalt(Ii)
• (R,R)-(-)-N,N-bis(3,5-di-T-butylsalicylid -ene)-
• (R,R)-Co(salen)
• (R,R)-Jacobsen HKR catalyst
• (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminatocobalt(II)
• (SP-4-2)-[[2,2′-[(1R,2R)-1,2-Cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]cobalt
• 2,2'-{(1R,2R)-cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)-cobalt (1:1)
• Cobalt, [[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, (SP-4-2)-
• Cobalt, [[2,2′-[1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)phenolato]](2-)-N,N′,O,O′]-, [SP-4-2-(1R-trans)]-
• Cobalt, [[2,2′-[1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, [SP-4-2-(1R-trans)]-
• N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-diaminocyclohexanecobalt(II)
• [[2,2′-[(1R,2R)-1,2-Cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]cobalt
• (1R,2R)-(-)-1,2-cyclohexanediamino-N,N'-bis-(3,5-di-t-butylsalicylidene)cobalt (II)
• (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(II)

(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

CAS: 176763-62-5

• Formula: C₃₆H₅₂CoN₂O₂
• Purity: 95%
• Color and Shape: Solid
• Molecular weight: 603.7434800000003

(R,R)-N,N?-Bis(3,5-Di-Tert-Butylsalicylidene)-1,2-Cyclohexanediaminocobalt(II)

CAS: 176763-62-5

• Purity: 98%
• Molecular weight: 603.74g/mol

(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

CAS: 176763-62-5

• Formula: C₃₆H₅₂CoN₂O₂
• Purity: >95.0%(T)
• Color and Shape: Red to Dark red powder to crystal
• Molecular weight: 603.76

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II), 98%

CAS: 176763-62-5

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. …

• Formula: C₃₆H₅₄CoN₂O₂
• Purity: 98%
• Color and Shape: Powder, Orange to red-brown
• Molecular weight: 605.77

(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

CAS: 176763-62-5

• Formula: C₃₆H₅₂CoN₂O₂
• Molecular weight: 603.76

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

CAS: 176763-62-5

• Purity: 99%
• Color and Shape: Solid
• Molecular weight: 603.336073904

(1R,2R)-(-)-1,2-Cyclo­hexanediamino-N,N'-bis(3,5-di-t-butyl­salicylidene)cobalt(II)

CAS: 176763-62-5

(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(II)

• Formula: C₃₆H₅₂CoN₂O₂
• Color and Shape: red-brown pwdr.
• Molecular weight: 603.76

(R,R)-(-)-N,N'-Bis(3,5-ditert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

CAS: 176763-62-5

• Formula: C₃₆H₅₂CoN₂O₂
• Color and Shape: Neat
• Molecular weight: 603.74

(R,R)-(-)-N,N'-Bis(3,5-ditert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

CAS: 176763-62-5

(R,R)-(-)-N,N'-Bis(3,5-ditert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) is a chiral ligand that is used in asymmetric synthesis. It can be prepared …

• Formula: C₃₆H₅₂CoN₂O₂
• Purity: Min. 95%
• Molecular weight: 603.74 g/mol