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CAS 178177-04-3

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(RAC)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)DIFLUOROTITANIUM(IV)

Description:
(RAC)-Ethylene bis(4,5,6,7-tetrahydro-1-indenyl)difluorotitanium(IV) is a coordination compound featuring titanium in a +4 oxidation state, characterized by its unique ligand structure. The compound contains two tetrahydro-1-indenyl groups, which contribute to its steric and electronic properties, enhancing its reactivity in various chemical processes. The presence of difluoro substituents on the titanium center influences its coordination chemistry and stability. This compound is typically used in catalytic applications, particularly in polymerization reactions, due to its ability to facilitate the formation of polymers with specific architectures. Its chiral nature, indicated by the (RAC) designation, suggests that it may exhibit interesting stereochemical properties, which can be significant in asymmetric synthesis. Additionally, the compound's solubility and reactivity can be affected by the presence of the fluorine atoms, which can alter the electronic environment around the titanium center. Overall, (RAC)-Ethylene bis(4,5,6,7-tetrahydro-1-indenyl)difluorotitanium(IV) is a notable compound in organometallic chemistry with potential applications in advanced materials and catalysis.
Formula:C20H26F2Ti
InChI:InChI=1/C20H26.2FH.Ti/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12,17-18H,1-8,13-14H2;2*1H;/q;;;+2/p-2/t17-,18?;;;/m0.../s1/rC20H26.F2Ti/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;1-3-2/h9-12,17-18H,1-8,13-14H2;/t17-,18?;/m0./s1
SMILES:C1CCC2=C(C1)C=CC2CCC1C=CC2=C1CCCC2.F.F.[Ti]
Synonyms:
  • (S,S)-Ethylenebis(4,5,6,7-Tetrahydro-1-Indenyl)Difluorotitanium(Iv)
  • (1'R)-1,1'-ethane-1,2-diylbis-4,5,6,7-tetrahydro-1H-indene - difluorotitanium (1:1)
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