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CAS 18107-18-1

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Trimethylsilyldiazomethane

Description:
Trimethylsilyldiazomethane (TMS-Diazomethane) is a chemical compound characterized by its use as a reagent in organic synthesis, particularly for the methylation of various substrates. It features a diazo functional group, which is known for its reactivity, allowing it to participate in various chemical transformations. The presence of the trimethylsilyl group enhances its stability and solubility in organic solvents, making it a valuable tool in synthetic chemistry. TMS-Diazomethane is typically handled with caution due to its potential hazards, including toxicity and explosiveness under certain conditions. It is often utilized in the preparation of methyl esters and in the synthesis of nitrogen-containing compounds. Additionally, its ability to generate reactive intermediates makes it useful in the formation of carbon-carbon bonds. Overall, TMS-Diazomethane is an important reagent in the toolkit of organic chemists, facilitating a range of reactions while requiring careful handling due to its reactive nature.
Formula:C4H10N2Si
InChI:InChI=1/C4H10N2Si/c1-7(2,3)4-6-5/h4H,1-3H3
InChI key:InChIKey=ONDSBJMLAHVLMI-UHFFFAOYSA-N
SMILES:C([Si](C)(C)C)=[N+]=[N-]
Synonyms:
  • (Diazomethyl)(Trimethyl)Silane
  • (Diazomethyl)trimethylsilane
  • Diazo((trimethylsilyl))methane
  • Methanediazonium, (trimethylsilyl)-, inner salt
  • Silane, (diazomethyl)trimethyl-
  • Trimethylsilyldiazomethane
  • (TRIMETHYLSILYL)DIAZOMETHANE
  • (trimethylsilyl)diazomethanesolution
  • (Trimethylsilyl)diazomethane, ca. 2.0M solution in hexanes
  • Trimethylsilyldiazomethane2.0MINdiethylester
  • See more synonyms
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