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CAS 181418-64-4

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Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)titanium (III) [Ti(TMHD)3]

Description:
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)titanium(III), commonly referred to as Ti(TMHD)3, is a coordination compound characterized by its complex structure involving titanium in a +3 oxidation state coordinated to three bidentate ligands, specifically 2,2,6,6-tetramethyl-3,5-heptanedione (TMHD). This compound typically exhibits a dark-colored appearance, often ranging from deep red to brown, and is known for its solubility in organic solvents, making it useful in various applications, including as a precursor in chemical vapor deposition (CVD) processes for titanium oxide films. Ti(TMHD)3 is notable for its thermal stability and relatively low volatility, which are advantageous for its use in thin-film deposition techniques. Additionally, the steric bulk of the TMHD ligands contributes to the compound's stability and influences its reactivity. Safety considerations should be taken into account when handling this compound, as it may pose health risks if inhaled or ingested. Overall, Ti(TMHD)3 is a significant compound in materials science and nanotechnology.
Formula:C33H57O6Ti
InChI:InChI=1/3C11H20O2.Ti/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
SMILES:CC(C)(C)C(=CC(=O)C(C)(C)C)O.CC(C)(C)C(=CC(=O)C(C)(C)C)O.CC(C)(C)C(=CC(=O)C(C)(C)C)O.[Ti]
Synonyms:
  • (Z)-2,2,6,6-tetramethyl-5-oxo-hept-3-en-3-olate
  • Titanium(+3) Cation
  • Tris(2,2,6,6tetramethyl-3,5-heptanedionato)yttrium(Ⅲ)(Triglyme Adduct)
  • Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)titanium (III) [Ti(TMHD)3]
  • Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)titanium(III), min. 97% [Ti(TMHD)3]
  • TI(TMHD)3
  • Tris-(2,2,6,6-tetramethyl-3,5-heptandionato)titanium(III)
  • TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)TITANIUM (III)
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