CymitQuimica logo

CAS 18467-77-1

:

(-)-2,3:4,6-di-O-isopropylidene-2-keto-L-gulonic acid

Description:
(-)-2,3:4,6-Di-O-isopropylidene-2-keto-L-gulonic acid, with the CAS number 18467-77-1, is a chemical compound that belongs to the class of carbohydrates, specifically a derivative of L-gulonic acid. This compound features two isopropylidene protecting groups, which enhance its stability and solubility in organic solvents. The presence of a keto group at the 2-position distinguishes it from other sugar derivatives, influencing its reactivity and potential applications in organic synthesis. The stereochemistry of the molecule is significant, as it is the (-)-enantiomer, which can exhibit different biological activities compared to its counterpart. Typically, compounds like this are utilized in the synthesis of more complex molecules, including pharmaceuticals and other bioactive compounds. Its structural characteristics, including the arrangement of hydroxyl groups and the ketone functionality, contribute to its chemical behavior, making it a valuable intermediate in synthetic organic chemistry.
Formula:C12H18O7
InChI:InChI=1/C12H18O7/c1-10(2)15-5-6-7(17-10)8-12(16-6,9(13)14)19-11(3,4)18-8/h6-8H,5H2,1-4H3,(H,13,14)
InChI key:InChIKey=FWCBATIDXGJRMF-FLNNQWSLSA-N
SMILES:C(O)(=O)[C@]12[C@]([C@]3([C@@](O1)(COC(C)(C)O3)[H])[H])(OC(C)(C)O2)[H]
Synonyms:
  • (-)-2,3:4,6-Di-O-isopropylidene-2-keto-<span class="text-smallcaps">L</span>-gulonic acid
  • (3aS,3bR,7aS,8aR)-2,2,5,5-tetramethyltetrahydro-8aH-[1,3]dioxolo[4,5]furo[3,2-d][1,3]dioxine-8a-carboxylic acid (non-preferred name)
  • 2,2,5,5-tetramethyltetrahydro-8aH-[1,3]dioxolo[4,5]furo[3,2-d][1,3]dioxine-8a-carboxylic acid (non-preferred name)
  • 2,3:4,6-Bis-O-(1-methylethylidene)-α-<span class="text-smallcaps">L</span>-xylo-2-hexulofuranosonic acid
  • 2,3:4,6-Di-O-isopropylidene-<span class="text-smallcaps">L</span>-xylo-hexulosonic acid
  • 2,3:4,6-Diacetone-2-ketogulonic acid
  • 2,3:4,6-Diisopropylidene-2-keto-<span class="text-smallcaps">L</span>-gulonic acid
  • 2,3:4,6-di-O-isopropylidene-alpha-L-xylo-2-hexulofuranosonic acid
  • 2-Keto-<span class="text-smallcaps">L</span>-gulonic acid, diacetone deriv.
  • 7H-1,3-Dioxolo[4,5]furo[3,2-d][1,3]dioxin, α-<span class="text-smallcaps">L</span>-xylo-2-hexulofuranosonic acid deriv.
  • See more synonyms
Sort by
The purity filter is not visible because current products do not have associated purity data for filtering.
Found 1 products.