CAS 185812-86-6
:PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
Description:
Palladium (I) tri-tert-butylphosphine bromide is a coordination compound featuring palladium in a low oxidation state, specifically +1. This compound is characterized by its coordination with tri-tert-butylphosphine, a bulky phosphine ligand that stabilizes the palladium center. The presence of bromide as a counterion contributes to the compound's overall stability and solubility in organic solvents. Typically, palladium complexes are known for their catalytic properties, particularly in cross-coupling reactions and other organic transformations. The steric bulk of the tri-tert-butylphosphine ligand can influence the reactivity and selectivity of the palladium complex in various chemical reactions. Additionally, this compound may exhibit unique electronic properties due to the combination of the palladium metal and the phosphine ligand, making it of interest in both synthetic and materials chemistry. Safety precautions should be observed when handling this compound, as palladium and its complexes can pose health risks.
Formula:C12H27BrPPd
InChI:InChI=1/C12H27P.BrH.Pd/c1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-9H3;1H;/q;;+1/p-1/rC12H27P.BrPd/c1-10(2,3)13(11(4,5)6)12(7,8)9;1-2/h1-9H3;
SMILES:CC(C)(C)P(C(C)(C)C)C(C)(C)C.Br.[Pd]
Synonyms:- Di-Bromobis(Tri-T-Butylphosphino)Dipalladium (I)
- Palladium (I) Tri-Tert-Butylphosphine Bromide, Dimer
- Bromo(tri-tert-butylphosphine)palladium(I)dimer
- Di--Bromobis(Tri-Tert-Butylphosphino)Dipalladium(I)
- Di-mu-bromobis(tri-t-butylphosphino)dipalladium(I)
- Dibromobis(tri-tert-butylphosphine)dipalladium
- Dibromobis(tri-tert-butylphosphine)dipalladium(I)
- Bromopalladium
- Tritert-Butylphosphane
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Found 3 products.
Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I)
CAS:<p>Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di--bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig ami</p>Formula:C24H56Br2P2Pd2Color and Shape:Crystals or crystalline powder, Dark green or greenish-blueMolecular weight:779.31Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I)
CAS:<p>Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I)</p>Formula:Pd2Br2P(C4H9)3Color and Shape:dark-green xtl.Molecular weight:777.28Palladium, di-μ-bromobis[tris(1,1-dimethylethyl)phosphine]di-, (Pd-Pd)
CAS:Formula:C24H56Br2P2Pd2Purity:98%Color and Shape:SolidMolecular weight:779.2970


