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CAS 185913-98-8

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(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

Description:
(R)-(+)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl is a chiral organophosphorus compound notable for its application in asymmetric catalysis. This compound features a biphenyl backbone with two diphenylphosphino groups, which contribute to its ability to facilitate enantioselective reactions. The presence of dichloro and dimethoxy substituents enhances its solubility and reactivity, making it a valuable ligand in coordination chemistry. The chirality of the molecule is significant, as it can influence the stereochemical outcome of reactions in which it is involved. Its structural characteristics allow it to form stable complexes with transition metals, which are often used as catalysts in various organic transformations. The compound is typically handled with care due to the presence of chlorine atoms, which can pose environmental and health risks. Overall, this substance is an important tool in synthetic organic chemistry, particularly in the development of new methodologies for the synthesis of chiral compounds.
Formula:C38H30Cl2O2P2
InChI:InChI=1/C38H30Cl2O2P2/c1-41-37-31(39)23-25-33(43(27-15-7-3-8-16-27)28-17-9-4-10-18-28)35(37)36-34(26-24-32(40)38(36)42-2)44(29-19-11-5-12-20-29)30-21-13-6-14-22-30/h3-26H,1-2H3
SMILES:COc1c(ccc(c1c1c(ccc(c1OC)Cl)P(c1ccccc1)c1ccccc1)P(c1ccccc1)c1ccccc1)Cl
Synonyms:
  • (-)-5,5'-Dichloro-2,2'-Bis(Diphenylphosphino)-6,6'-Dimethoxy-1,1'-Biphenyl
  • (-)-(5,5'-Dichloro-6,6'-Dimethoxy-1,1'-Biphenyl)-2,2'-Diyl-Bis(Diphenylphosphine)
  • (-)-2,2'-Bis(Diphenylphosphino)-5,5'-Dichloro-6,6'-Dimethoxy-1,1'-Biphenyl
  • (R)-Cl-Meo-Biphep
  • (5,5'-Dichloro-6,6'-Dimethoxybiphenyl-2,2'-Diyl)Bis(Diphenylphosphane)
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