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CAS 1907-33-1

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Lithium t-butoxide

Description:
Lithium t-butoxide, with the CAS number 1907-33-1, is an organolithium compound characterized by its strong basicity and nucleophilicity. It is typically encountered as a white to off-white solid or as a solution in organic solvents. The compound is formed by the reaction of lithium hydroxide with t-butyl alcohol, resulting in the formation of lithium t-butoxide and water. It is commonly used as a reagent in organic synthesis, particularly in deprotonation reactions and as a base in various coupling reactions. Due to its strong basic nature, it can effectively deprotonate weak acids, making it valuable in the formation of carbanions. Additionally, lithium t-butoxide is known for its stability under anhydrous conditions, although it can react vigorously with moisture, releasing t-butanol and lithium hydroxide. Safety precautions are essential when handling this compound, as it can be hazardous if not managed properly. Overall, lithium t-butoxide is a versatile reagent in the field of organic chemistry, facilitating a range of synthetic transformations.
Formula:C4H9LiO
InChI:InChI=1/C4H9O.Li/c1-4(2,3)5;/h1-3H3;/q-1;+1/rC4H9LiO/c1-4(2,3)6-5/h1-3H3
InChI key:InChIKey=UOHBMRODJBFDPN-UHFFFAOYSA-N
SMILES:C(C)(C)(C)O.[Li]
Synonyms:
  • (1,1-Dimethylethoxy)lithium
  • 2-Methyl-2-propanol lithium salt
  • 2-Propanol, 2-methyl-, lithium salt
  • 2-Propanol, 2-methyl-, lithium salt (1:1)
  • Lithium 2-Methylpropan-2-Olate
  • Lithium tert-butanolate
  • Lithium tert-butoxide
  • Lithium tert-butoxide solution
  • Lithium tert-butylate
  • Lithiumtbutoxide
  • See more synonyms
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