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CAS 19845-69-3

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1,6-Bis(diphenylphosphino)hexane

Description:
1,6-Bis(diphenylphosphino)hexane, with the CAS number 19845-69-3, is a bidentate ligand commonly used in coordination chemistry and catalysis. This compound features a hexane backbone with two diphenylphosphino groups attached at the 1 and 6 positions, which enhances its ability to chelate metal ions. The presence of the phosphine groups provides strong donor properties, making it effective in stabilizing various metal complexes, particularly in transition metal catalysis. The ligand exhibits good solubility in organic solvents, which is advantageous for its application in organic synthesis and catalysis. Additionally, its structural flexibility allows for the formation of stable complexes with a range of metals, including palladium and platinum, facilitating reactions such as cross-coupling and hydrogenation. The steric and electronic properties of the diphenylphosphino groups contribute to the ligand's effectiveness in promoting reactivity and selectivity in catalytic processes. Overall, 1,6-Bis(diphenylphosphino)hexane is a valuable compound in the field of organometallic chemistry and catalysis.
Formula:C30H32P2
InChI:InChI=1/C30H32P2/c1(15-25-31(27-17-7-3-8-18-27)28-19-9-4-10-20-28)2-16-26-32(29-21-11-5-12-22-29)30-23-13-6-14-24-30/h3-14,17-24H,1-2,15-16,25-26H2
SMILES:C(CCCP(c1ccccc1)c1ccccc1)CCP(c1ccccc1)c1ccccc1
Synonyms:
  • Hexane-1,6-diylbis(diphenylphosphine)
  • Phosphine, 1,1'-(1,6-Hexanediyl)Bis[1,1-Diphenyl-
  • Hexane-1,6-Diylbis(Diphenylphosphane)
  • Hexamethylenebis(Diphenylphosphine)
  • Dpph
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