CAS 19978-61-1
:Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II)
Description:
Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), commonly referred to as Pd(dppf)Cl2, is a coordination complex of palladium with notable applications in catalysis, particularly in cross-coupling reactions such as the Suzuki and Stille reactions. This compound features a palladium center coordinated to two chloride ions and a bidentate ligand, 1,2-bis(diphenylphosphino)ethane (dppf), which enhances its stability and reactivity. The presence of the diphenylphosphino groups provides strong σ-donor and π-acceptor properties, facilitating the formation of reactive palladium species during catalytic processes. Pd(dppf)Cl2 is typically a yellow to orange solid and is soluble in organic solvents, making it suitable for various organic synthesis applications. Its ability to form stable complexes with substrates and its effectiveness in promoting C-C bond formation are key characteristics that make it a valuable reagent in synthetic organic chemistry. Proper handling and storage under inert conditions are recommended due to its sensitivity to moisture and air.
Formula:C26H24Cl2P2Pd
InChI:InChI=1/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/rC26H26Cl2P2Pd/c27-31(28)29(23-13-5-1-6-14-23,24-15-7-2-8-16-24)21-22-30(31,25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20,29-30H,21-22H2
SMILES:c1ccc(cc1)P1(CCP(c2ccccc2)(c2ccccc2)[Pd]1(Cl)Cl)c1ccccc1
Synonyms:- (1,2-Bis(Diphenylphosphino)Ethane)-Dichloropallad
- DichlorobisdiphenylphosphinoethanepalladiumIIorange
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
- Palladium(2+) Dichloride Ethane-1,2-Diylbis(Diphenylphosphane) (1:1)
- 1,2-Bis(diphenylphosphino)ethane palladium(II) chloride
- [1,2-Bis(Diphenylphosphino)Ethane]Palladium(Ii) Dichloride
- Dichloro[Bis(1,2-Diphenylphosphino)Ethane]Palladium(Ii)
- Dichlorobis(1,2-diphenylphosphino)ethaneüpalladium(II)
- Dichloro[1,2-bis(diphenylphosphino)-ethane]palladium
- Dichloro[1,2-bis(diphenylphosphino)ethane palladium(II)]
- Dichloro[1,2-bis(diphenylphosphino)ethane palladium (II)]
- Dichloro[bis(1,2-diphenylphosphino)ethane]palladium(II), Pd 18.5%
- Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II),98%
- Dichloro[1,2-bis(diphenylphosphano)ethane]palladium(II)
- Dichloro[1,2-bis(diphenylphosphino)ethanepalladiu
- Dichloro (1,2-Bis (diphenylphosphino)ethane dichlorpalladium (II))
- See more synonyms
Sort by
Purity (%)
0
100
|
0
|
50
|
90
|
95
|
100
Found 9 products.
[1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride
CAS:Formula:C26H24Cl2P2PdPurity:>98.0%(T)Color and Shape:White to Yellow to Green powder to crystalMolecular weight:575.75Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98%
CAS:Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98%
Formula:PdCl2(C6H5)2PCH2CH2P(C6H5)2Purity:98%Color and Shape:off-white pwdr.Molecular weight:575.74Palladium, dichloro[1,2-ethanediylbis[diphenylphosphine-kP]]-,(SP-4-2)-
CAS:Formula:C26H24Cl2P2PdPurity:97%Color and Shape:SolidMolecular weight:575.7423[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
CAS:[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)Formula:·C26H24P2·Cl2PdPurity:95%Color and Shape: solidMolecular weight:575.74g/mol[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
CAS:Controlled ProductApplications [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is a precatalyst used in the production of acrylic acid sodium salt via coupling of CO2 with ethene.
References Vavasori, A.; et al.: Pure Appl. Chem., 90, 315 (2018).Formula:C26H24Cl2P2PdColor and Shape:NeatMolecular weight:575.74Dichloro(1,2-bis(Diphenylphosphino)Ethane)Palladium (II) extrapure, 98%
CAS:Formula:C26H24Cl2P2PColor and Shape:Light orange, PowderMolecular weight:575.7[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
CAS:Controlled Product[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is a chemical compound that is insoluble in water and soluble in organic solvents. It is a reagent used to prepare other compounds. The synthesis of this compound involves the reaction of chloroform with dichloro[1,2-bis(diphenylphosphino)ethane]palladium (II). The resulting compound has a yellow color due to its ligands, which are amines or halides. This compound can be recrystallized from toluene or ether for use in preparative work. [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) has been used as an analytical reagent for the determination of chloride and ligand content in some organic solvents.Formula:C26H24Cl2P2PdPurity:Min. 95%Molecular weight:575.74 g/mol
![[1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride](/_next/image/?url=https%3A%2Fstatic.cymitquimica.com%2Fproducts%2F3B%2Fthumb%2FB2016.jpg&w=3840&q=75)
![Palladium, dichloro[1,2-ethanediylbis[diphenylphosphine-kP]]-,(SP-4-2)-](/_next/image/?url=https%3A%2Fstatic.cymitquimica.com%2Fproducts%2FIN%2Fthumb%2FDA00I3PL.jpg&w=3840&q=75)
![[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)](/_next/image/?url=https%3A%2Fstatic.cymitquimica.com%2Fproducts%2F54%2Fthumb%2FOR46570.jpg&w=3840&q=75)
![[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)](/_next/image/?url=https%3A%2Fstatic.cymitquimica.com%2Fproducts%2F10%2Fthumb%2FF551796.jpg&w=3840&q=75)
![[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)](/_next/image/?url=https%3A%2Fstatic.cymitquimica.com%2Fproducts%2FTR%2Fthumb%2FB430490.jpg&w=3840&q=75)
![[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)](/_next/image/?url=https%3A%2Fstatic.cymitquimica.com%2Fproducts%2F3D%2Fthumb%2FFB54999.jpg&w=3840&q=75)
