CAS 203714-71-0

dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1)

Description:

Dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1), with CAS number 203714-71-0, is a coordination compound featuring a ruthenium center coordinated to both a phosphine ligand and a substituted phenyl group. This compound typically exhibits characteristics common to organometallic complexes, including a notable ability to participate in catalytic reactions, particularly in olefin metathesis. The presence of the tricyclohexylphosphane ligand enhances the stability and solubility of the complex in organic solvents. The dichloro substituents contribute to the reactivity of the ruthenium center, allowing for various transformations in synthetic chemistry. Additionally, the steric and electronic properties of the 1-methylethoxy group can influence the overall reactivity and selectivity of the compound in catalytic applications. Overall, this compound exemplifies the intricate interplay between metal coordination, ligand design, and catalytic function in organometallic chemistry.

Formula: C₂₈H₄₅Cl₂OPRu

InChI: InChI=1/C18H33P.C10H12O.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8(2)11-10-7-5-4-6-9(10)3;;;/h16-18H,1-15H2;3-8H,1-2H3;2*1H;/q;;;;+2/p-2/rC18H33P.C10H12Cl2ORu/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8(2)13-10-6-4-3-5-9(10)7-14(11)12/h16-18H,1-15H2;3-8H,1-2H3

SMILES: C1CCC(CC1)P(C1CCCCC1)C1CCCCC1.CC(C)[O+]=C1C=CC=CC1=[CH-].Cl.Cl.[Ru]

Synonyms:

• Hoveyda-Grubbs Catalyst 1st Generation
• Dichloro(O-Isopropoxyphenylmethylene)(Tricyclohexylphosphine)Ruthenium(Ii)

Hoveyda-Grubbs Catalyst 1st Generation

CAS: 203714-71-0

Formula: C₂₈H₄₅Cl₂OPRu

Purity: 98%

Color and Shape: Solid

Molecular weight: 600.6061

Ref: IN-DA003503

Dichloro(2-Isopropoxyphenylmethylene)(Tricyclohexylphosphine)Ruthenium (II)

CAS: 203714-71-0

Dichloro(2-Isopropoxyphenylmethylene)(Tricyclohexylphosphine)Ruthenium (II)

Purity: 98%

Molecular weight: 600.61g/mol

Ref: 54-IN10433

Hoveyda-Grubbs 1st

CAS: 203714-71-0

Purity: 98%

Color and Shape: Solid

Molecular weight: 601.17

Ref: 10-F996253

Hoveyda-Grubbs Catalyst 1st Generation

Controlled Product

CAS: 203714-71-0

Applications Hoveyda-Grubbs Catalyst 1st Generation is a ruthenium-based olefin metathesis catalyst.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Kingsbury, J.S. et al.: Journal of the American Chemical Society, 121, 791 (1999);

Formula: C₂₈H₄₅Cl₂OPRu

Color and Shape: Neat

Molecular weight: 600.61

Ref: TR-H700520