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CAS 205064-10-4

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(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate

Description:
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate is a chiral rhodium complex that serves as a catalyst in various organic reactions, particularly in asymmetric synthesis. This compound features a rhodium center coordinated to a cyclooctadiene ligand and two phospholano groups, which contribute to its stereochemical properties and catalytic activity. The presence of the tetrafluoroborate counterion enhances its solubility in polar solvents, making it suitable for a range of catalytic applications. The specific stereochemistry of the phospholano ligands imparts chirality to the complex, allowing it to facilitate enantioselective transformations. This compound is typically used in reactions such as hydrogenation and other processes where chiral catalysts are required to produce optically active products. Its stability and reactivity are influenced by the electronic and steric properties of the ligands, making it a valuable tool in synthetic organic chemistry. Safety precautions should be observed when handling this compound, as with many metal complexes, due to potential toxicity and reactivity.
Formula:C18H28P2
Synonyms:
  • Bisdimethylphospholanobenzenecyclooctadienerhodium
  • (+)-1,2-Bis[(2S,5S)-dimethylphospholano)benzene(cyclooctadiene]rhodium(I) BF4
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