CAS 212143-23-2

Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

Description:

Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) is a chiral organometallic compound that features a ruthenium center coordinated to a bidentate ligand system. The compound is characterized by its use of a binaphthyl backbone, which imparts chirality, and diphenylphosphine groups that enhance its coordination properties. The presence of the ruthenium(II) ion allows for various oxidation states, making it a versatile catalyst in asymmetric synthesis, particularly in reactions such as hydrogenation and cross-coupling. The dichloro ligands contribute to its reactivity and stability, while the chiral ligands facilitate enantioselective transformations. This compound is typically utilized in research settings for its ability to promote specific stereochemical outcomes in organic reactions. Its structural complexity and the presence of multiple functional groups make it an important subject of study in the field of organometallic chemistry and catalysis.

Formula: C₅₈H₄₈Cl₂N₂P₂Ru

InChI: InChI=1S/C44H32P2.C14H16N2.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h1-32H;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1

SMILES: c1ccc(cc1)P(c1ccccc1)c1ccc2ccccc2c1c1c2ccccc2ccc1P(c1ccccc1)c1ccccc1.c1ccc(cc1)C(C(c1ccccc1)N)N.Cl.Cl.[Ru]

Synonyms:

• dichloro((r)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)((1r,2r)-(+)-1,2-diphenylethylenediamine)ruthenium(ii)

Dichloro[(R)-(+)-2,2'-bis(diphenyl­phosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenyl­ethylenediamine]ruthenium(II), min. 90%

CAS: 212143-23-2

Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), min. 90%

Formula: C₅₈H₄₈Cl₂N₂P₂Ru

Purity: min. 90%

Color and Shape: white to pale yellow pwdr.

Molecular weight: 1006.96

Ref: 08-44-0220

Dichloro[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine)ruthenium(II)

CAS: 212143-23-2

Formula: C₅₈H₄₈Cl₂N₂P₂Ru

Purity: 98%

Color and Shape: Solid

Molecular weight: 1006.9386

Ref: IN-DA003PD2

Dichloro[(R)-(+)-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl][(1R,2R)-(+)-1,2-Diphenylethylenediamine]Ruthenium(II)

CAS: 212143-23-2

Dichloro[(R)-(+)-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl][(1R,2R)-(+)-1,2-Diphenylethylenediamine]Ruthenium(II)

Purity: 98%

Molecular weight: 1006.93g/mol

Ref: 54-IN12114

Dichloro[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine)ruthenium(II)

CAS: 212143-23-2

Purity: 98%

Molecular weight: 1006.17

Ref: 10-F552097

Dichloro[(R)-(+)-2,2²-bis(diphenylphosphino)-1,1²-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine)ruthenium(II)

CAS: 212143-23-2

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Formula: C₅₈H₄₈Cl₂N₂P₂Ru

Purity: Min. 95%

Molecular weight: 1,006.94 g/mol

Ref: 3D-MIA14323