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CAS 213343-65-8

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Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2S,2′S,5S,5′S)-1,1′-(1,2-ethanediyl)bis[2,5-dimethylphospholane-κP]]-, tetrafluoroborate(1-) (1:1)

Description:
Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2S,2′S,5S,5′S)-1,1′-(1,2-ethanediyl)bis[2,5-dimethylphospholane-κP]]-, tetrafluoroborate(1-) is a coordination compound featuring rhodium in a +1 oxidation state, complexed with a cyclooctadiene ligand and a bidentate phosphine ligand. This compound exhibits unique characteristics due to the presence of the cyclooctadiene, which contributes to its stability and reactivity. The tetrafluoroborate anion serves as a counterion, enhancing the solubility of the complex in polar solvents. The stereochemistry of the phosphine ligand, which is derived from a chiral source, may impart interesting chiral properties to the complex, potentially making it useful in asymmetric synthesis. The compound is likely to be sensitive to air and moisture, necessitating careful handling and storage. Its applications may include catalysis in organic reactions, particularly in processes requiring transition metal catalysts. Overall, this compound exemplifies the intricate interplay between metal coordination chemistry and ligand design, showcasing the versatility of rhodium complexes in various chemical applications.
Formula:C22H40BF4P2Rh
InChI:InChI=1/C14H28P2.C8H12.BF4.Rh/c1-11-5-6-12(2)15(11)9-10-16-13(3)7-8-14(16)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11-14H,5-10H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t11-,12-,13-,14-;;;/m0.../s1
InChI key:InChIKey=CVUPEPGZCZHSOF-FZUZUFHQSA-N
SMILES:C[C@@H]1[P]2([Rh+]345([P]6([C@@H](C)CC[C@@H]6C)CC2)[CH]7=[CH]3CC[CH]4=[CH]5CC7)[C@@H](C)CC1.[B+3]([F-])([F-])([F-])[F-]
Synonyms:
  • Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2S,2′S,5S,5′S)-1,1′-(1,2-ethanediyl)bis[2,5-dimethylphospholane-κP]]-, tetrafluoroborate(1-)
  • Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2S,2′S,5S,5′S)-1,1′-(1,2-ethanediyl)bis[2,5-dimethylphospholane-κP]]-, tetrafluoroborate(1-) (1:1)
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