CAS 213343-66-9

Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-ethanediyl)bis[2,5-diethylphospholane-κP]]-, tetrafluoroborate(1-) (1:1)

Description:

Rhodium(1+), specifically in the form of the complex described, is a coordination compound featuring rhodium in a +1 oxidation state. This compound is characterized by its unique ligand environment, which includes a cyclooctadiene and a bidentate phosphine ligand, contributing to its stability and reactivity. The presence of the tetrafluoroborate anion indicates that it is a salt, which can influence its solubility and ionic properties. The phosphine ligands enhance the electron-donating ability of the complex, making it potentially useful in catalysis, particularly in reactions involving organic transformations. The specific arrangement of the ligands around the rhodium center can lead to interesting stereochemical properties, which may affect its reactivity and interaction with substrates. Additionally, the compound's stability and behavior in various solvents can be influenced by the bulky ethyl groups on the phosphine ligands. Overall, this rhodium complex exemplifies the intricate interplay between metal centers and ligands in coordination chemistry, with potential applications in synthetic and catalytic processes.

Formula: C₂₆H₄₈P₂Rh·BF₄

InChI: InChI=1S/C18H36P2.C8H12.BF4.Rh/c1-5-15-9-10-16(6-2)19(15)13-14-20-17(7-3)11-12-18(20)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h15-18H,5-14H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/t15-,16-,17-,18-;;;/m1.../s1

InChI key: InChIKey=BGAGRLBYPPBYLY-JDKOHWMVSA-N

SMILES: C(C)[C@H]1[P]2([Rh+]345([P]6([C@H](CC)CC[C@H]6CC)CC2)[CH]7=[CH]3CC[CH]4=[CH]5CC7)[C@H](CC)CC1.[B+3]([F-])([F-])([F-])[F-]

Synonyms:

• Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-ethanediyl)bis[2,5-diethylphospholane-κP]]-, tetrafluoroborate(1-)
• Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-ethanediyl)bis[2,5-diethylphospholane-κP]]-, tetrafluoroborate(1-) (1:1)

1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane(cyclooctadiene)rhodium(I) tetrafluoroborate

CAS: 213343-66-9

1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane(cyclooctadiene)rhodium(I) tetrafluoroborate

Formula: C₂₆H₄₈BF₄P₂Rh

Color and Shape: orange-red solid

Molecular weight: 612.32

Ref: 08-45-3010

1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane(cyclooctadiene)rhodium(I) tetrafluoroborate

CAS: 213343-66-9

1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane(cyclooctadiene)rhodium(I) tetrafluoroborate

Purity: 98%

Molecular weight: 610.3g/mol

Ref: 54-IN12762

Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-ethanediyl)bis[2,5-diethylphospholane-κP]]-, tetrafluoroborate(1-) (1:1)

CAS: 213343-66-9

Formula: C₂₆H₄₈BF₄P₂Rh

Purity: 98%

Color and Shape: Solid

Molecular weight: 612.317

Ref: IN-DA01RTFI