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CAS 213343-69-2

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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE,98+%(S,S)-ME-BPE-RH

Description:
The chemical substance known as (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE, with the CAS number 213343-69-2, is a chiral rhodium complex that serves as a catalyst in various asymmetric reactions, particularly in organic synthesis. This compound features a rhodium center coordinated to a bidentate ligand derived from a phospholane structure, which enhances its catalytic activity and selectivity. The presence of the trifluoromethanesulfonate counterion contributes to its solubility and stability in polar solvents. The specific stereochemistry of the ligand, characterized by the (S,S) configuration, is crucial for its effectiveness in promoting enantioselective transformations. Typically, such complexes are utilized in reactions like hydrogenation and other processes where chirality is essential. The high purity level of 98% or greater indicates its suitability for research and industrial applications, ensuring consistent performance in catalytic cycles. Overall, this compound exemplifies the intersection of coordination chemistry and asymmetric synthesis, highlighting the importance of metal-ligand interactions in catalysis.
Formula:C14H28P2·C8H12·CF3O3S·Rh
Synonyms:
  • (+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate, 97%
  • (1,2-Bis((S,S)-2,5-dimethyl-1-phospholidinyl)ethane)(1,5-cyclooctadiene)rhodium(1+) trifluoromethanesulfonate
  • (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate
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