CAS 21947-87-5

Bis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]borane

Description:

Bis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]borane, with the CAS number 21947-87-5, is an organoboron compound characterized by its unique bicyclic structure. This compound features two boron atoms bonded to a bicyclo[3.1.1]heptane framework, which is further substituted with trimethyl groups at specific positions, contributing to its steric bulk and potential reactivity. The stereochemistry indicated by the (1S,2R,3S,5S) configuration suggests that the compound has specific spatial arrangements that can influence its chemical behavior and interactions. Organoboron compounds like this one are often utilized in organic synthesis, particularly in reactions involving nucleophiles and electrophiles, due to the versatile reactivity of the boron atom. Additionally, the presence of the bicyclic structure may impart unique physical properties, such as solubility and stability, which are important for its applications in various chemical processes. Overall, this compound exemplifies the complexity and utility of organoboron chemistry in synthetic organic chemistry.

Formula: C₂₀H₃₅B

InChI: InChI=1S/C20H35B/c1-11-15-7-13(19(15,3)4)9-17(11)21-18-10-14-8-16(12(18)2)20(14,5)6/h11-18,21H,7-10H2,1-6H3/t11-,12-,13+,14+,15-,16-,17-,18-/m0/s1

InChI key: InChIKey=KBGJOMVTAXYPAG-NAVXHOJHSA-N

SMILES: CC1(C)[C@]2(C[C@@]1(C[C@H](B[C@@H]3[C@@H](C)[C@]4(C(C)(C)[C@@](C3)(C4)[H])[H])[C@H]2C)[H])[H]

Synonyms:

• (+)-Diisopinocampheyl borane
• Bis(2,6,6-Trimethylbicyclo[3.1.1]Hept-3-Yl)Borane
• Bis(d-isopinocampheyl)borane
• Bis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]borane
• Borane, bis(2,6,6-trimethylbicyclo[3.1.1]hept-3-yl)-, [1S-[1α,2β,3α(1R*,2S*,3R*,5R*),5α]]-
• Borane, bis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-
• Borane, di-3-pinanyl-, (+)-
• d-Diisopinocampheylborane
• (+)-Diisopinocampheylborane
• Diisopinocampheylborane
• (+)-Diisopinocampheylborane