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CAS 220114-38-5

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Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

Description:
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), with CAS number 220114-38-5, is a chiral organometallic compound that features a ruthenium center coordinated to various ligands, including a bidentate phosphine and a chiral diamine. This compound is characterized by its robust coordination chemistry, which allows it to participate in asymmetric catalysis, particularly in reactions such as hydrogenation and cross-coupling. The presence of the bulky 3,5-xylyl groups on the phosphine ligands contributes to its steric properties, enhancing its selectivity in catalytic processes. The binaphthyl backbone provides a rigid structure that is crucial for maintaining the chiral environment around the metal center. Additionally, the dichloro substituents facilitate the activation of the ruthenium center, making it a versatile catalyst in synthetic organic chemistry. Overall, this compound exemplifies the intersection of coordination chemistry and asymmetric synthesis, showcasing the importance of ligand design in catalysis.
Formula:C66H64Cl2N2P2Ru
Synonyms:
  • RuCl2[(R)-xylbinap][(R,R)-dpen]
  • Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
  • RuCl2[(R)-DM-BINAP][(R,R)-DPEN]
  • [(R)−
  • DM−
  • 2
  • Dichloro{(R)-(+)-2,2'
  • BINAP][(R,R)−
  • Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen]
  • -binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(
  • RuCl
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