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CAS 261948-85-0

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Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Description:
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) is a coordination complex featuring a ruthenium center coordinated to a bidentate ligand derived from binaphthyl and diphenylphosphine groups. This compound is characterized by its chiral nature, attributed to the (S)-configuration of the binaphthyl moiety, which imparts specific stereochemical properties that are significant in asymmetric catalysis. The diacetato ligands provide additional stability and influence the electronic properties of the ruthenium center, enhancing its reactivity in various chemical transformations. Typically, this complex exhibits a distinctive color, often ranging from red to purple, depending on its environment and concentration. It is soluble in organic solvents, making it suitable for use in organic synthesis and catalysis. The compound is particularly noted for its role in facilitating enantioselective reactions, such as hydrogenation and cross-coupling processes, due to the chiral environment created by the ligand framework. Its applications in synthetic organic chemistry underscore its importance in the development of chiral pharmaceuticals and fine chemicals.
Formula:C48H38O4P2Ru
Synonyms:
  • Ruthenium, bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]-, (OC-6-22)-
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