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CAS 28110-70-5

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Chromium (III) tetraphenylporphine chloride

Description:
Chromium (III) tetraphenylporphine chloride is a coordination compound featuring a chromium ion coordinated to a tetraphenylporphyrin ligand, which is a macrocyclic structure known for its ability to stabilize metal ions. This compound typically exhibits a deep color, often purple or violet, due to the electronic transitions within the porphyrin ring. The presence of the chloride ion indicates that it is a salt, which can influence its solubility and reactivity. Chromium (III) in this context is in a +3 oxidation state, which is common for porphyrin complexes and contributes to the stability and electronic properties of the compound. The tetraphenylporphyrin ligand provides a planar structure that allows for effective π-π stacking interactions and can facilitate electron transfer processes. This compound is of interest in various fields, including catalysis, photochemistry, and as a potential model for biological systems involving heme-like structures. Its unique properties make it a valuable subject of study in coordination chemistry and materials science.
Formula:C44H28ClCrN4
InChI:InChI=1/C44H28N4.ClH.Cr/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40u;;
SMILES:c1ccc(cc1)C1=c2ccc(=C(c3ccccc3)C3=NC(=C(c4ccccc4)c4ccc(C(=C5C=CC1=N5)c1ccccc1)[n-]4)C=C3)[n-]2.Cl.[Cr]
Synonyms:
  • Chromiumtetraphenylporphinechloride
  • Chromium(III) tetraphenylporphine chloride
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