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CAS 309-89-7

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Bis(η5-2,4-cyclopentadien-1-yl)difluorotitanium

Description:
Bis(η5-2,4-cyclopentadien-1-yl)difluorotitanium, with the CAS number 309-89-7, is a coordination compound featuring titanium in a low oxidation state, typically +2. This compound is characterized by its unique structure, which includes two cyclopentadienyl (Cp) ligands that are bound to the titanium center in a η5 (eta five) coordination mode, indicating that all five carbon atoms of each Cp ring are involved in bonding. The presence of two fluorine atoms in the difluoro substituents contributes to its reactivity and stability. This compound is often used in organometallic chemistry and catalysis, particularly in polymerization processes. Its properties include volatility and sensitivity to moisture, which necessitates careful handling under inert atmospheres. Additionally, it exhibits interesting electronic properties due to the presence of the transition metal titanium, making it a subject of study in various chemical applications, including materials science and synthetic chemistry.
Formula:C10H10F2Ti
InChI:InChI=1S/2C5H5.2FH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q2*-1;;;+4/p-2
InChI key:InChIKey=GXGRCAOLDUZLDC-UHFFFAOYSA-L
SMILES:[F-][Ti+4]12345678([F-])([CH]=9[CH]1=[CH]2[CH-]3[CH]49)[CH]=%10[CH]5=[CH]6[CH-]7[CH]8%10
Synonyms:
  • Titanium, bis(η5-2,4-cyclopentadien-1-yl)difluoro-
  • Bis(η5-2,4-cyclopentadien-1-yl)difluorotitanium
  • Dicyclopentadienyltitanium(IV) difluoride
  • Titanium, difluorodicyclopentadienyl-
  • Dicyclopentadienyldifluorotitanium
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