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CAS 31126-95-1

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Rhodium(II) trifluoroacetate dimer

Description:
Rhodium(II) trifluoroacetate dimer, with the CAS number 31126-95-1, is a coordination compound featuring rhodium in a +2 oxidation state, coordinated with trifluoroacetate ligands. This compound typically exists as a dimer, meaning two rhodium centers are linked through bridging ligands, which can influence its reactivity and stability. Rhodium(II) trifluoroacetate is known for its role as a catalyst in various organic reactions, particularly in C-H activation and carbon-carbon bond formation. The trifluoroacetate ligands contribute to the compound's solubility in organic solvents and can enhance its reactivity due to the electron-withdrawing nature of the trifluoromethyl groups. The compound is generally characterized by its distinct coordination geometry, often exhibiting a square planar arrangement around the rhodium centers. Additionally, it is sensitive to air and moisture, necessitating careful handling and storage under inert conditions. Overall, Rhodium(II) trifluoroacetate dimer is a valuable reagent in synthetic chemistry, particularly in catalysis and organometallic chemistry.
Formula:C8F12O8Rh2
InChI:InChI=1/4C2HF3O2.2Rh/c4*3-2(4,5)1(6)7;;/h4*(H,6,7);;/q;;;;2*+2/p-4
SMILES:C(=O)(C(F)(F)F)O.C(=O)(C(F)(F)F)O.C(=O)(C(F)(F)F)O.C(=O)(C(F)(F)F)O.[Rh].[Rh]
Synonyms:
  • Rhodiumtrifluoroacetate
  • Rhodium - Trifluoroacetic Acid (1:2)
  • Acetic Acid, Trifluoro-, Rhodium(2+) Salt
  • Rhodium(Ⅱ) trifluoroacetate, dimer
  • Rhodium(II) trifluoroacetate
  • Rhodium(I) trifluoroacetate dimer
  • Bis-(trifluoroacetic acid rhodium salt)
  • Dirhodium(II) Tetrakis(trifluoroacetate)
  • RhodiuM(II) trifluoroacetate diMer, Rh2(CF3COO)4
  • Rhodium(II) trifluoroacetate dimer, min. 95%
  • See more synonyms
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