CAS 32760-80-8

Iron(1+), (η5-2,4-cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]-, hexafluorophosphate(1-) (1:1)

Description:

The chemical substance known as Iron(1+), (η5-2,4-cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]-, hexafluorophosphate(1-) (1:1) is a coordination complex featuring iron in a +1 oxidation state. This compound is characterized by its unique ligand environment, which includes a cyclopentadienyl anion and an isopropyl-substituted aromatic system, contributing to its stability and reactivity. The hexafluorophosphate anion serves as a counterion, providing ionic balance and enhancing solubility in polar solvents. The presence of the cyclopentadienyl ligand indicates potential for π-backbonding, which can influence the electronic properties of the iron center. This complex may exhibit interesting magnetic and electronic characteristics due to the low oxidation state of iron, making it a subject of interest in organometallic chemistry and catalysis. Its structural and electronic properties can be further explored through various spectroscopic techniques, which can provide insights into its bonding and reactivity patterns.

Formula: C₁₄H₁₇Fe·F₆P

InChI: InChI=1S/C9H12.C5H5.F6P.Fe/c1-8(2)9-6-4-3-5-7-9;1-2-4-5-3-1;1-7(2,3,4,5)6;/h3-8H,1-2H3;1-5H;;/q;2*-1;+2

InChI key: InChIKey=AGOCNVHYNVDYAJ-UHFFFAOYSA-N

SMILES: C(C)(C)C1=2[Fe+2]3456789%10([CH]1=[CH]3[CH]4=[CH]5[CH]62)[CH-]%11[CH]7=[CH]8[CH]9=[CH]%10%11.[P+5]([F-])([F-])([F-])([F-])([F-])[F-]

Synonyms:

• (5-Cyclopentadienyl)(6-isopropylbenzene)iron(1+) hexafluorophosphate
• (6-Cumene)(5-cyclopentadienyl)iron(II) hexafluorophosphate
• (η⁵-2,4-Cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]iron(1+) hexafluorophosphate
• (η⁵-2,4-Cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]iron(1+) hexafluorophosphate(1-)
• (η⁵-Cyclopentadienyl)(η⁶-isopropylbenzene)iron(1+) hexafluorophosphate
• (η⁶-Cumene)(η⁵-cyclopentadienyl)iron(II) hexafluorophosphate
• Benzene, (1-methylethyl)-, iron complex
• Cg 24-61
• Cg 261
• Cyclopentadienylcumeniron hexafluorophosphate
• I 261
• Irgacure 261
• Irgacure CG 24-61
• Iron(1+), (.Eta.5-2,4-Cyclopentadien-1-Yl)(1,2,3,4,5,6-.Eta.)-(1-Methylethyl)Benzene-, Hexafluorophosphate(1-)
• Iron(1+), (cumene)-π-cyclopentadienyl-, hexafluorophosphate(1-)
• Iron(1+), (η⁵-2,4-cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]-, hexafluorophosphate(1-)
• Iron(1+), (η⁵-2,4-cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]-, hexafluorophosphate(1-) (1:1)
• Phosphate(1-), hexafluoro-, (η⁵-2,4-cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]iron(1+)
• R-Gen 261
• Uv 261
• Iron(1+), (η5-2,4-cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]-, hexafluorophosphate(1-)
• Iron(1+), (η5-2,4-cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]-, hexafluorophosphate(1-) (1:1)
• Phosphate(1-), hexafluoro-, (η5-2,4-cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]iron(1+)
• LOTCURE 261
• (cumene)cyclopentadienyliron(II) hexafluorophosphate
• (PI6-Cumene)-(PI5-cyclopentadienyl)-iron hexafluorophosphate
• Iron(1+), (.eta.5-2,4-cyclopentadien-1-yl)(1,2,3,4,5,6-.eta.)-(1-methylethyl)benzene-, hexafluorophosphate(1-), 94%-106%+
• (cumene)cyclopentadienyliron(ii) hexa-fluorophosp
• (η-cyclopentadienyl)(η-cumenyl)iron(1+)hexafluorophosphate(1-)
• (h-Cyclopentadienyl)(h-cumenyl)eisen(1+) hexafluorophosphat(1-)
• (η6-cumene)(η5-cyclopentadienyl)iron hexafluorophosphate
• η5-2,4-Cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene] iron(1+) hexa-fluorophosphate(1-)

(Cumene)cyclopentadienyliron(II) Hexafluorophosphate

CAS: 32760-80-8

Formula: C₁₄H₁₇F₆FeP

Purity: >95.0%(T)(N)

Color and Shape: White to Brown powder to crystal

Molecular weight: 386.10

Ref: 3B-C3751

Iron(1+), (.eta.5-2,4-cyclopentadien-1-yl)(1,2,3,4,5,6-.eta.)-(1-methylethyl)benzene-, hexafluorophosphate(1-)

CAS: 32760-80-8

Formula: C₁₄H₁₇F₆FeP

Purity: 95%

Color and Shape: Solid

Molecular weight: 386.0940

Ref: IN-DA00CMG5

(η5-2,4-Cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]iron hexafluorophosphate

CAS: 32760-80-8

(η5-2,4-Cyclopentadien-1-yl)[(1,2,3,4,5,6-η)-(1-methylethyl)benzene]iron hexafluorophosphate

Purity: 95%

Molecular weight: 386.09g/mol

Ref: 54-IN12621