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CAS 32965-49-4

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chloro(1,5-hexadiene)rhodium(I) dimer

Description:
Chloro(1,5-hexadiene)rhodium(I) dimer is a coordination complex featuring rhodium as the central metal atom, coordinated with a chloro ligand and a diene ligand, specifically 1,5-hexadiene. This compound typically exists as a dimer, meaning two rhodium centers are linked together, which can influence its reactivity and stability. The rhodium(I) oxidation state indicates that the metal is in a low oxidation state, which is common for complexes that participate in catalytic processes, particularly in organic synthesis. The presence of the diene ligand suggests potential for π-acceptor interactions, which can enhance the reactivity of the complex in various reactions, such as olefin metathesis or hydroformylation. The dimeric structure may also exhibit unique properties, such as altered solubility and reactivity compared to its monomeric counterparts. Overall, chloro(1,5-hexadiene)rhodium(I) dimer is of interest in organometallic chemistry and catalysis, particularly for its potential applications in synthetic organic chemistry.
Formula:C12H20Cl2Rh2
InChI:InChI=1/2C6H10.2ClH.2Rh/c2*1-3-5-6-4-2;;;;/h2*3-4H,1-2,5-6H2;2*1H;;/p-2
SMILES:C=CCCC=C.C=CCCC=C.[Cl-].[Cl-].[Rh].[Rh]
Synonyms:
  • 1,5-Hexadiene, Chloride, Rhodium Salt (2:2:1)
  • Chloro(1,5-hexadiene)rhodium(I),dimer
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