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CAS 32993-05-8

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Chloro(η5-cyclopentadienyl)bis(triphenylphosphine)ruthenium

Description:
Chloro(η5-cyclopentadienyl)bis(triphenylphosphine)ruthenium, with the CAS number 32993-05-8, is a coordination complex of ruthenium that features a cyclopentadienyl ligand and two triphenylphosphine ligands. This compound typically exhibits a square planar geometry around the ruthenium center, which is characteristic of many d6 metal complexes. The presence of the η5-cyclopentadienyl ligand contributes to the stability and reactivity of the complex, while the triphenylphosphine ligands enhance its solubility in organic solvents and can influence its electronic properties. The compound is often used in catalysis, particularly in reactions involving olefins and in the synthesis of various organic compounds. Its reactivity can be attributed to the ability of the ruthenium center to undergo oxidation and reduction, making it a versatile catalyst in organic synthesis. Additionally, the compound's stability and solubility make it suitable for various applications in organometallic chemistry and materials science.
Formula:C41H35ClP2Ru
InChI:InChI=1S/2C18H15P.C5H5.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h2*1-15H;1-5H;1H;/q;;-1;;+2/p-1
InChI key:InChIKey=QHMOWPJARYQHOB-UHFFFAOYSA-M
SMILES:[P]([Ru+2]1234([P](C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7)([Cl-])[CH-]8[CH]1=[CH]2[CH]3=[CH]48)(C9=CC=CC=C9)(C%10=CC=CC=C%10)C%11=CC=CC=C%11
Synonyms:
  • Bis(triphenylphosphine)(chloro)cyclopentadienylruthenium
  • Bis(triphenylphosphine)(cyclopentadiene)ruthenium chloride
  • Bis(triphenylphosphine)cyclopentadienylruthenium chloride
  • Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium
  • Chloro(η-cyclopentadienyl)bis(triphenylphosphine)ruthenium
  • Chloro(η<sup>5</sup>-2,4-cyclopentadien-1-yl)bis(triphenylphosphine)ruthenium
  • Chloro(η<sup>5</sup>-cyclopentadienyl)bis(triphenylphosphine)ruthenium
  • Chloro-π-cyclopentadienylbis(triphenylphosphine)ruthenium
  • Chlorocyclopentadienylbis(Triphenylphosphine)Ruthenium(Ii)
  • Cp(PPh3)2RuCl
  • See more synonyms
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