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CAS 346457-41-8

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Diacetato[(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthyl]ruthenium(II)

Description:
Diacetato[(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthyl]ruthenium(II) is a coordination complex featuring ruthenium as the central metal ion, coordinated with a bidentate ligand derived from binaphthyl and diphenylphosphine groups. This compound is characterized by its chiral nature, attributed to the (R)-enantiomer of the binaphthyl ligand, which imparts specific stereochemical properties. The presence of acetate groups enhances its solubility and reactivity, making it useful in various catalytic applications, particularly in asymmetric synthesis. The ruthenium center typically exhibits a +2 oxidation state, contributing to its stability and reactivity in catalytic cycles. This complex is often employed in organic transformations, including hydrogenation and cross-coupling reactions, due to its ability to facilitate the formation of carbon-carbon bonds. Additionally, the steric and electronic properties of the diphenylphosphine ligands influence the reactivity and selectivity of the catalyst, making it a valuable tool in synthetic organic chemistry. Overall, this compound exemplifies the intersection of coordination chemistry and catalysis, showcasing the utility of transition metal complexes in modern chemical synthesis.
Synonyms:
  • Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-5,5’-bis(diphenylphosphino)-4,4’-bi-1,3-benzodioxole]diruthenate(II)
  • (R)-Ru(OAc)2(BINAP)
  • (R)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2]
  • Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis(diphenylphosphino)-4,4μ-bi-1,3-benzodioxole]diruthenate(II)
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